Literature DB >> 25343222

N-heterocyclic carbene-main-group chemistry: a rapidly evolving field.

Yuzhong Wang1, Gregory H Robinson.   

Abstract

This Award Article targets the evolving, yet surprisingly fruitful, chemistry of N-heterocyclic carbenes with low-oxidation-state main-group elements. Specifically, the chemistry of carbene-stabilized diatomic allotropes, diborenes, gallium octahedra, beryllium borohydride, and a host of related compounds will be presented. Providing a valuable historical perspective, the foundational work concerning the organometallic chemistry of gallium with sterically demanding m-terphenyl ligands from this laboratory will also be discussed.

Entities:  

Year:  2014        PMID： 25343222     DOI： 10.1021/ic502231m

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  11 in total

1.  Main group chemistry: Small silicon oxides isolated.

Authors:  Yitzhak Apeloig
Journal:  Nat Chem       Date:  2015-06       Impact factor: 24.427

2.  Stabilization of elusive silicon oxides.

Authors:  Yuzhong Wang; Mingwei Chen; Yaoming Xie; Pingrong Wei; Henry F Schaefer; Paul von R Schleyer; Gregory H Robinson
Journal:  Nat Chem       Date:  2015-04-20       Impact factor: 24.427

3.  Generation of 1,2-azaboretidines via reduction of ADC borane adducts.

Authors:  H Braunschweig; A Gackstatter; T Kupfer; T Scheller; F Hupp; A Damme; N Arnold; W C Ewing
Journal:  Chem Sci       Date:  2015-04-16       Impact factor: 9.825

4.  Direct estimate of the internal π-donation to the carbene centre within N-heterocyclic carbenes and related molecules.

Authors:  Diego M Andrada; Nicole Holzmann; Thomas Hamadi; Gernot Frenking
Journal:  Beilstein J Org Chem       Date:  2015-12-24       Impact factor: 2.883

5.  From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond.

Authors:  Chelladurai Ganesamoorthy; Christoph Helling; Christoph Wölper; Walter Frank; Eckhard Bill; George E Cutsail; Stephan Schulz
Journal:  Nat Commun       Date:  2018-01-08       Impact factor: 14.919

6.  Phosphine and carbene azido-cations: [(L)N3]+ and [(L)2N3].

Authors:  Daniel Winkelhaus; Michael H Holthausen; Roman Dobrovetsky; Douglas W Stephan
Journal:  Chem Sci       Date:  2015-07-21       Impact factor: 9.825

7.  Cationic Phosphorus Compounds Based on a Bis(1-piperidinyl)-Substituted Carbodiphosphorane: Syntheses, Structures, and Csp3 -H Activation.

Authors:  Alexander Kroll; Henning Steinert; Mike Jörges; Tim Steinke; Bert Mallick; Viktoria H Gessner
Journal:  Organometallics       Date:  2020-08-26       Impact factor: 3.876

8.  N-Heterocyclic Carbenes Carrying Weakly Coordinating Anions.

Authors:  Luong Phong Ho; Matthias Tamm
Journal:  Chemistry       Date:  2022-04-27       Impact factor: 5.020

Review 9.  Phosphorus-ylides: powerful substituents for the stabilization of reactive main group compounds.

Authors:  Abir Sarbajna; V S V S N Swamy; Viktoria H Gessner
Journal:  Chem Sci       Date:  2020-07-17       Impact factor: 9.825

10.  Rhodium and Iridium Complexes of Anionic Thione and Selone Ligands Derived from Anionic N-Heterocyclic Carbenes.

Authors:  Luong Phong Ho; Angelika Neitzel; Thomas Bannenberg; Matthias Tamm
Journal:  Chemistry       Date:  2021-12-22       Impact factor: 5.020
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