Literature DB >> 25341414

Do thermal diffusion and Dufour coefficients satisfy Onsager's reciprocity relation?

Alois Würger1.   

Abstract

It is commonly admitted that in liquids the thermal diffusion and Dufour coefficients D(T) and D(F) satisfy Onsager's reciprocity. From their relation to the cross-coefficients of the phenomenological equations, we are led to the conclusion that this is not the case in general. As illustrative and physically relevant examples, we discuss micellar solutions and colloidal suspensions, where D(T) arises from chemical reactions or viscous effects but is not related to the Dufour coefficient D(F). The situation is less clear for binary molecular mixtures; available experimental and simulation data do not settle the question whether D(T) and DF are reciprocal coefficients.

Year:  2014        PMID: 25341414     DOI: 10.1140/epje/i2014-14096-y

Source DB:  PubMed          Journal:  Eur Phys J E Soft Matter        ISSN: 1292-8941            Impact factor:   1.890


  23 in total

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2.  Measurement of thermodiffusion coefficient in n-alkane binary mixtures: composition dependence.

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Journal:  J Phys Chem B       Date:  2010-05-27       Impact factor: 2.991

3.  Molecular and thermal diffusion coefficients of alkane-alkane and alkane-aromatic binary mixtures: effect of shape and size of molecules.

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Journal:  J Phys Chem B       Date:  2007-01-11       Impact factor: 2.991

4.  Thermodiffusion in model nanofluids by molecular dynamics simulations.

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Journal:  J Chem Phys       Date:  2008-02-14       Impact factor: 3.488

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Journal:  Langmuir       Date:  2010-06-01       Impact factor: 3.882

7.  Thermophobicity of liquids: heats of transport in mixtures as pure component properties.

Authors:  S Hartmann; G Wittko; W Köhler; K I Morozov; K Albers; G Sadowski
Journal:  Phys Rev Lett       Date:  2012-08-10       Impact factor: 9.161

8.  Specific salt effects on thermophoresis of charged colloids.

Authors:  Kyriakos A Eslahian; Arghya Majee; Michael Maskos; Alois Würger
Journal:  Soft Matter       Date:  2014-03-28       Impact factor: 3.679

9.  Thermal diffusion and molecular diffusion values for some alkane mixtures: a comparison between thermogravitational column and thermal diffusion forced rayleigh scattering.

Authors:  Pablo Blanco; Pavel Polyakov; M Mounir Bou-Ali; Simone Wiegand
Journal:  J Phys Chem B       Date:  2008-06-21       Impact factor: 2.991

10.  The "macromolecular tourist": universal temperature dependence of thermal diffusion in aqueous colloidal suspensions.

Authors:  S Iacopini; R Rusconi; R Piazza
Journal:  Eur Phys J E Soft Matter       Date:  2006-01-31       Impact factor: 1.624

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  2 in total

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Journal:  Eur Phys J E Soft Matter       Date:  2015-04-29       Impact factor: 1.890

Review 2.  A unified description of colloidal thermophoresis.

Authors:  Jérôme Burelbach; Daan Frenkel; Ignacio Pagonabarraga; Erika Eiser
Journal:  Eur Phys J E Soft Matter       Date:  2018-01-16       Impact factor: 1.890

  2 in total

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