Literature DB >> 25336023

Magnetic blocking in extended metal atom chains: a pentachromium(II) complex behaving as a single-molecule magnet.

A Cornia1, L Rigamonti, S Boccedi, R Clérac, M Rouzières, L Sorace.   

Abstract

Compound [Cr5(tpda)4Cl2] (H2tpda = N(2),N(6)-di(pyridin-2-yl)pyridine-2,6-diamine), an Extended Metal Atom Chain complex featuring two quadruply-bonded {Cr2} units, exhibits field-induced slow relaxation of its magnetization arising from the terminal chromium(II) ion and provides the first example of a chromium(II)-based Single-Molecule Magnet.

Entities:  

Year:  2014        PMID： 25336023     DOI： 10.1039/c4cc06693f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Ferromagnetic ground state for a hypothetical iron-based extended metal atom chain.

Authors:  Paweł Szarek; Wojciech Wegner; Wojciech Grochala
Journal:  J Mol Model       Date:  2016-02-24       Impact factor: 1.810

2.  Tetrairon(II) extended metal atom chains as single-molecule magnets.

Authors:  Alessio Nicolini; Marco Affronte; Daniel J SantaLucia; Marco Borsari; Benjamin Cahier; Matteo Caleffi; Antonio Ranieri; John F Berry; Andrea Cornia
Journal:  Dalton Trans       Date:  2021-06-08       Impact factor: 4.569

3.  The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?

Authors:  Jamie M Frost; Katie L M Harriman; Muralee Murugesu
Journal:  Chem Sci       Date:  2015-12-23       Impact factor: 9.825

4.  Cr(i)Cl as well as Cr+ are stabilised between two cyclic alkyl amino carbenes.

Authors:  Prinson P Samuel; Roman Neufeld; Kartik Chandra Mondal; Herbert W Roesky; Regine Herbst-Irmer; Dietmar Stalke; Serhiy Demeshko; Franc Meyer; Vallyanga Chalil Rojisha; Susmita De; Pattiyil Parameswaran; A Claudia Stückl; Wolfgang Kaim; Jonathan H Christian; Jasleen K Bindra; Naresh S Dalal
Journal:  Chem Sci       Date:  2015-03-20       Impact factor: 9.825

5.  Three Gd-based magnetic refrigerant materials with high magnetic entropy: From di-nuclearity to hexa-nuclearity to octa-nuclearity.

Authors:  Minmin Wang; Chengyuan Sun; Yujia Gao; Hong Xue; Ling Huang; Yutian Xie; Jin Wang; Yuanyuan Peng; Yanfeng Tang
Journal:  Front Chem       Date:  2022-09-29       Impact factor: 5.545

6.  The Origin of Magnetic Anisotropy and Single-Molecule Magnet Behavior in Chromium(II)-Based Extended Metal Atom Chains.

Authors:  Andrea Cornia; Anne-Laure Barra; Vladimir Bulicanu; Rodolphe Clérac; Miguel Cortijo; Elizabeth A Hillard; Rita Galavotti; Alessandro Lunghi; Alessio Nicolini; Mathieu Rouzières; Lorenzo Sorace; Federico Totti
Journal:  Inorg Chem       Date:  2020-01-22       Impact factor: 5.165
  6 in total

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