Literature DB >> 25333657

Enabling catalytic ketone hydrogenation by frustrated Lewis pairs.

Tayseer Mahdi1, Douglas W Stephan.   

Abstract

Hydrogenation of alkyl and aryl ketones using H2 is catalytically achieved in 18 examples using 5 mol % B(C6F5)3 in an ethereal solvent. In these cases the borane and ether behave as a frustrated Lewis pair to activate H2 and effect the reduction.

Entities:  

Year:  2014        PMID： 25333657     DOI： 10.1021/ja508829x

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  20 in total

1.  Halogenated triphenylgallium and -indium in frustrated Lewis pair activations and hydrogenation catalysis.

Authors:  Maotong Xu; Josephine Possart; Alexander E Waked; Julie Roy; Werner Uhl; Douglas W Stephan
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2017-08-28       Impact factor: 4.226

2.  Design and reactions of a carbon Lewis base/boron Lewis acid frustrated Lewis pair.

Authors:  Jennifer Möricke; Birgit Wibbeling; Constantin G Daniliuc; Gerald Kehr; Gerhard Erker
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2017-08-28       Impact factor: 4.226

Review 3.  On the concept of frustrated Lewis pairs.

Authors:  Frédéric-Georges Fontaine; Douglas W Stephan
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2017-08-28       Impact factor: 4.226

4.  Optimizing the Energetics of FLP-Type H2 Activation by Modulating the Electronic and Structural Properties of the Lewis Acids: A DFT Study.

Authors:  Mojgan Heshmat; Bernd Ensing
Journal:  J Phys Chem A       Date:  2020-07-29       Impact factor: 2.781

5.  Versatile Catalytic Hydrogenation Using A Simple Tin(IV) Lewis Acid.

Authors:  Daniel J Scott; Nicholas A Phillips; Joshua S Sapsford; Arron C Deacy; Matthew J Fuchter; Andrew E Ashley
Journal:  Angew Chem Int Ed Engl       Date:  2016-10-24       Impact factor: 15.336

6.  Hydrogen activation using a novel tribenzyltin Lewis acid.

Authors:  Robert T Cooper; Joshua S Sapsford; Roland C Turnell-Ritson; Dong-Hun Hyon; Andrew J P White; Andrew E Ashley
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2017-08-28       Impact factor: 4.226

7.  Metal-free electrocatalytic hydrogen oxidation using frustrated Lewis pairs and carbon-based Lewis acids.

Authors:  Elliot J Lawrence; Ewan R Clark; Liam D Curless; James M Courtney; Robin J Blagg; Michael J Ingleson; Gregory G Wildgoose
Journal:  Chem Sci       Date:  2016-01-06       Impact factor: 9.825

8.  Expanding Water/Base Tolerant Frustrated Lewis Pair Chemistry to Alkylamines Enables Broad Scope Reductive Aminations.

Authors:  Valerio Fasano; Michael J Ingleson
Journal:  Chemistry       Date:  2017-01-18       Impact factor: 5.236

9.  Facile Protocol for Water-Tolerant "Frustrated Lewis Pair"-Catalyzed Hydrogenation.

Authors:  Daniel J Scott; Trevor R Simmons; Elliot J Lawrence; Gregory G Wildgoose; Matthew J Fuchter; Andrew E Ashley
Journal:  ACS Catal       Date:  2015-08-17       Impact factor: 13.084

10.  A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis.

Authors:  Jeffrey M Farrell; Roy T Posaratnanathan; Douglas W Stephan
Journal:  Chem Sci       Date:  2015-01-26       Impact factor: 9.825
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