Literature DB >> 25327999

Hydroarylations of heterobicyclic alkenes through rhodium-catalyzed directed C-H functionalizations of S-aryl sulfoximines.

Wanrong Dong1, Kanniyappan Parthasarathy, Ying Cheng, Fangfang Pan, Carsten Bolm.   

Abstract

Rhodium-catalyzed directed CH-functionalizations have been used in hydroarylations of heterobicyclic alkenes with NH-sulfoximines. Unexpectedly, the bicyclic framework is retained, resulting in the formation of addition products being attractive intermediates for functionalized molecules that are difficult to prepare by other means.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  CH activation; heterobicyclic alkenes; hydroarylation reaction; rhodium; sulfoximines

Year:  2014        PMID： 25327999     DOI： 10.1002/chem.201404859

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  2 in total

1.  Three-Component 1,2-Carboamidation of Bridged Bicyclic Alkenes via RhIII-Catalyzed Addition of C-H Bonds and Amidating Reagents.

Authors:  Daniel S Brandes; Ana Sirvent; Brandon Q Mercado; Jonathan A Ellman
Journal:  Org Lett       Date:  2021-03-19       Impact factor: 6.005

2.  Transfer of Electrophilic NH Using Convenient Sources of Ammonia: Direct Synthesis of NH Sulfoximines from Sulfoxides.

Authors:  Marina Zenzola; Robert Doran; Leonardo Degennaro; Renzo Luisi; James A Bull
Journal:  Angew Chem Int Ed Engl       Date:  2016-04-29       Impact factor: 15.336
  2 in total

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