Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Selective ruthenium-catalyzed methylation of 2-arylethanols using methanol as C1 feedstock.

Literature DB >> 25327955

Selective ruthenium-catalyzed methylation of 2-arylethanols using methanol as C1 feedstock.

Yang Li¹, Haoquan Li, Henrik Junge, Matthias Beller.

Abstract

We describe the selective cross coupling of methanol and 2-arylethanols using a combination of Ru-MACHO (RuHCl(PNP(Ph))CO) and Shvo's diruthenium complex as catalysts. The desired domino transformation takes place via so-called borrowing hydrogen methodology, which constitutes an ideal example of green chemistry.

Entities: Chemical

Year: 2014 PMID： 25327955 DOI： 10.1039/c4cc06933a

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

Keyword Cloud
Cited

10 in total

1. Enantioselective Formation of All-Carbon Quaternary Centers via C-H Functionalization of Methanol: Iridium-Catalyzed Diene Hydrohydroxymethylation.

Authors: Khoa D Nguyen; Daniel Herkommer; Michael J Krische
Journal: J Am Chem Soc Date: 2016-10-20 Impact factor: 15.419

2. Enantioselective Formation of CF₃-Bearing All-Carbon Quaternary Stereocenters via C-H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation.

Authors: Michael Holmes; Khoa D Nguyen; Leyah A Schwartz; Tom Luong; Michael J Krische
Journal: J Am Chem Soc Date: 2017-06-12 Impact factor: 15.419

10. Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for β-Alkylation of Secondary Alcohols with Primary Alcohols.

Authors: Yao Cui; Jixian Wang; Lei Yu; Ying Xu; David J Young; Haiyan Li; Hongxi Li
Journal: Polymers (Basel) Date: 2022-01-07 Impact factor: 4.329

10 in total

Selective ruthenium-catalyzed methylation of 2-arylethanols using methanol as C1 feedstock.

1. Enantioselective Formation of All-Carbon Quaternary Centers via C-H Functionalization of Methanol: Iridium-Catalyzed Diene Hydrohydroxymethylation.

2. Enantioselective Formation of CF₃-Bearing All-Carbon Quaternary Stereocenters via C-H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation.

Review 3. Borrowing Hydrogen for Organic Synthesis.

4. Manganese-Catalyzed β-Methylation of Alcohols by Methanol.

5. Carbon monoxide and hydrogen (syngas) as a C1-building block for selective catalytic methylation.

6. Allylic alcohol synthesis by Ni-catalyzed direct and selective coupling of alkynes and methanol.

7. Hydrogen-borrowing and interrupted-hydrogen-borrowing reactions of ketones and methanol catalyzed by iridium.

8. Iron-Catalyzed Borrowing Hydrogen β-C(sp³)-Methylation of Alcohols.

9. Manganese(I)-Catalyzed β-Methylation of Alcohols Using Methanol as C₁ Source.

10. Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for β-Alkylation of Secondary Alcohols with Primary Alcohols.