| Literature DB >> 25325709 |
L Čechová1, E Procházková, I Císařová, M Dračínský, Z Janeba.
Abstract
While purifying new polysubstituted 5-nitrosopyrimidines, the unique separation of pairs of rotamers as chemical species, stabilized by a single intramolecular hydrogen bond and differing only in nitroso group orientation, was achieved. This interesting stereochemical phenomenon is compared to the well-known atropisomerism.Entities:
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Year: 2014 PMID： 25325709 DOI： 10.1039/c4cc06978a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222