Literature DB >> 25319140

Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus-aluminum ligand to gold.

Marc Devillard1, Emmanuel Nicolas, Christian Appelt, Jana Backs, Sonia Mallet-Ladeira, Ghenwa Bouhadir, J Chris Slootweg, Werner Uhl, Didier Bourissou.   

Abstract

Coordination of Mes2PC(=CHPh)AltBu2 to metal chlorides has been studied. Bridging P→M-Cl→Al coordinations were observed with Rh and Pd fragments, while chloride abstraction systematically occurred with gold. The resulting zwitterionic complexes have been fully characterized and analyzed by DFT calculations.

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Year:  2014        PMID： 25319140     DOI： 10.1039/c4cc06992g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Attempted synthesis of ortho-phenylene phosphino-tritylium cations.

Authors:  Kantapat Chansaenpak; Mengxi Yang; François P Gabbaï
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2017-08-28       Impact factor: 4.226

2.  Expanding the allyl analogy: accessing η3-P,B,P diphosphinoborane complexes of group 10.

Authors:  Marcus W Drover; Jonas C Peters
Journal:  Dalton Trans       Date:  2018-03-12       Impact factor: 4.390

3.  H2 and carbon-heteroatom bond activation mediated by polarized heterobimetallic complexes.

Authors:  R Malcolm Charles; Timothy P Brewster
Journal:  Coord Chem Rev       Date:  2021-02-07       Impact factor: 22.315

4.  Gold(I) Complexes of the Geminal Phosphinoborane tBu2PCH2BPh2.

Authors:  Devin H A Boom; Andreas W Ehlers; Martin Nieger; Marc Devillard; Ghenwa Bouhadir; Didier Bourissou; J Chris Slootweg
Journal:  ACS Omega       Date:  2018-04-09

5.  Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation.

Authors:  Yiheng Wang; Zhen Hua Li; Huadong Wang
Journal:  RSC Adv       Date:  2018-07-23       Impact factor: 3.361
  5 in total

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