| Literature DB >> 25317924 |
David Schneider1, Tatiana Spallek, Cäcilia Maichle-Mössmer, Karl W Törnroos, Reiner Anwander.
Abstract
Homoleptic cerium(IV) diisopropylamide was synthesized via oxidation of ate complex Ce(NiPr2)4Li(thf) with trityl chloride or hexachloroethane. Due to its ready accessibility, and high pKa value of the proligand HNiPr2, Ce(NiPr2)4 features a promising candidate for protonolysis reactions, as shown for the synthesis of dimeric cerium(IV) tetrakis(1,1,3,3-N,N,N',N'-tetramethylguanidinate).Entities:
Year: 2014 PMID： 25317924 DOI： 10.1039/c4cc06228k
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222