Literature DB >> 25314360

Amide and N-oxide functionalization of T-shaped ligands for isoreticular MOFs with giant enhancements in CO2 separation.

Ying Xiong1, Yan-Zhong Fan, Rui Yang, Sha Chen, Mei Pan, Ji-Jun Jiang, Cheng-Yong Su.   

Abstract

By stepwise functionalization of a T-shaped ligand with amide and N-oxide groups, we obtained a MOF with drastically strengthened CO2-framework interactions, induced by a "open donor sites" (ODSs) effect, resulting in a high heat of adsorption and high CO2/CH4, CO2/CO and CO2/N2 separation selectivities at room temperature.

Entities:  

Year:  2014        PMID： 25314360     DOI： 10.1039/c4cc06697a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  A redetermination of the structure and Hirshfeld surface analysis of poly[di-aquadi-μ-hydroxido-tetra-kis-(μ-nicotinato N-oxide)tricopper(II)].

Authors:  Masoud Mirzaei; Maryam Bazargan; Pouria Ebtehaj; Joel T Mague
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2021-02-26

2.  MIL-53(Al) as a Versatile Platform for Ionic-Liquid/MOF Composites to Enhance CO2 Selectivity over CH4 and N2.

Authors:  Safiyye Kavak; H Mert Polat; Harun Kulak; Seda Keskin; Alper Uzun
Journal:  Chem Asian J       Date:  2019-07-24

3.  Coordination complexes of zinc and manganese based on pyridine-2,5-dicarboxylic acid N-oxide: DFT studies and antiproliferative activities consideration.

Authors:  Hanie Alizadeh; Masoud Mirzaei; Amir Sh Saljooghi; Vida Jodaian; Maryam Bazargan; Joel T Mague; Rosa M Gomila; Antonio Frontera
Journal:  RSC Adv       Date:  2021-11-22       Impact factor: 4.036

4.  Effects of N-oxidation on the molecular and crystal structures and properties of isocinchomeronic acid, its metal complexes and their supramolecular architectures: experimental, CSD survey, solution and theoretical approaches.

Authors:  Zahra Hosseini-Hashemi; Masoud Mirzaei; Ameneh Jafari; Peyman Hosseinpour; Mohammad Yousefi; Antonio Frontera; Mahmoud Lari Dashtbayaz; Mojtaba Shamsipur; Mehdi Ardalani
Journal:  RSC Adv       Date:  2019-08-14       Impact factor: 3.361

5.  Unusual adsorption behaviours and responsive structural dynamics via selective gate effects of an hourglass porous metal-organic framework.

Authors:  Ying Xiong; Yan-Zhong Fan; Zhang-Wen Wei; Cheng-Xia Chen; Sha Chen; Dawei Wang; Mihail Barboiu; Ji-Jun Jiang; Cheng-Yong Su
Journal:  RSC Adv       Date:  2019-11-14       Impact factor: 4.036
  5 in total

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