| Literature DB >> 25308125 |
A Lanza1, C Fiolka, M Fisch, N Casati, M Skoulatos, C Rüegg, K W Krämer, Piero Macchi.
Abstract
Pressure-driven orbital reordering in the quantum magnet [CuF2(H2O)2(pyz)], (pyz = pyrazine), dramatically affects its magnetic exchange interactions. The crystal chemistry of this system is enriched with a new phase above 3 GPa, surprisingly concomitant with other polymorphs. Moreover, we discovered an unprecedented compound with a different stoichiometry, [(CuF2(H2O)2)2(pyz)], featuring magnetic bi-layers.Entities:
Year: 2014 PMID： 25308125 DOI： 10.1039/c4cc06696k
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222