Literature DB >> 25307165

Direct enantiospecific substitution of primary α-aminoalkylferrocenes via Lewis acid-catalyzed C-N bond cleavage.

Meng-Guang Zhou1, Wen-Zhao Zhang, Shi-Kai Tian.   

Abstract

Highly enantioenriched primary α-aminoalkylferrocenes were found to undergo zinc chloride-catalyzed substitution with various carbon, nitrogen, and sulfur nucleophiles in an enantiospecific fashion through C-N bond cleavage. The reaction tolerates air and moisture and exhibits high atom-economy by releasing ammonia as the sole byproduct.

Entities:  

Year:  2014        PMID： 25307165     DOI： 10.1039/c4cc07196d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Enantiomeric-Enriched Ferrocenes: Synthesis, Chiral Resolution, and Mathematic Evaluation of CD-chiral Selector Energies with Ferrocene-Conjugates.

Authors:  Lubov V Snegur; Yurii A Borisov; Yuliya V Kuzmenko; Vadim A Davankov; Mikhail M Ilyin; Mikhail M Ilyin; Dmitry E Arhipov; Alexander A Korlyukov; Sergey S Kiselev; Alexander A Simenel
Journal:  Molecules       Date:  2017-08-25       Impact factor: 4.411

2.  Anomeric Stereoauxiliary Cleavage of the C-N Bond of d-Glucosamine for the Preparation of Imidazo[1,5-a]pyridines.

Authors:  Kui Zeng; Jin Ye; Xintong Meng; Sebastian Dechert; Martin Simon; Shuaiyu Gong; Ricardo A Mata; Kai Zhang
Journal:  Chemistry       Date:  2022-04-08       Impact factor: 5.020
  2 in total

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