Literature DB >> 25297879

I₂-catalyzed oxidative C(sp³)-H/S-H coupling: utilizing alkanes and mercaptans as the nucleophiles.

Jiwen Yuan1, Xu Ma, Hong Yi, Chao Liu, Aiwen Lei.   

Abstract

By using alkanes and mercaptans as the nucleophiles with di-tert-butyl peroxide (DTBP) as the oxidant, I2-catalyzed oxidative C(sp(3))-H/S-H coupling was achieved. This protocol provides a novel process to construct C(sp(3))-S bonds from commercially available hydrocarbons and mercaptans.

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Year:  2014        PMID： 25297879     DOI： 10.1039/c4cc05661b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Silver-catalyzed direct thiolation of quinones by activation of aryl disulfides to synthesize quinonyl aryl thioethers.

Authors:  Cheng Zhang; Jesse McClure; C James Chou
Journal:  J Org Chem       Date:  2015-04-27       Impact factor: 4.354

2.  A photoexcited halogen-bonded EDA complex of the thiophenolate anion with iodobenzene for C(sp3)-H activation and thiolation.

Authors:  Tao Li; Kangjiang Liang; Jiaying Tang; Yuzhen Ding; Xiaogang Tong; Chengfeng Xia
Journal:  Chem Sci       Date:  2021-10-21       Impact factor: 9.825

3.  Synthesis of β-Hydroxysulfides from Thiophenols and Disulfides with tert-Butyl Hydroperoxide as the Oxidant and Reactant.

Authors:  Jian-Bo Feng; Xiao-Feng Wu
Journal:  ChemistryOpen       Date:  2016-05-17       Impact factor: 2.911
  3 in total

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