Literature DB >> 25297520

Entrapment of elusive guests within metal-seamed nanocapsules.

Harshita Kumari1, Ping Jin, Simon J Teat, Charles L Barnes, Scott J Dalgarno, Jerry L Atwood.   

Abstract

Anions play a crucial role in locking alkali metals on the interior of metal-organic capsules that contain structural water gates. This role is further evidenced when stitching-up the capsule seam, resulting in either expulsion or trapping of cesium ions depending on the anion employed.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Keywords:  calixarenes; cesium; encapsulation; ion transport; supramolecular chemistry

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Year:  2014        PMID: 25297520     DOI: 10.1002/anie.201406776

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  1 in total

1.  Strong cation···π interactions promote the capture of metal ions within metal-seamed nanocapsule.

Authors:  Harshita Kumari; Ping Jin; Simon J Teat; Charles L Barnes; Scott J Dalgarno; Jerry L Atwood
Journal:  J Am Chem Soc       Date:  2014-11-26       Impact factor: 15.419

  1 in total

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