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Literature DB >> 25296263

Direct carboxylation of simple arenes with CO₂ through a rhodium-catalyzed C-H bond activation.

Takuya Suga¹, Hajime Mizuno, Jun Takaya, Nobuharu Iwasawa.

Abstract

Direct carboxylation of simple arenes under atmospheric pressure of CO2 is achieved through a rhodium-catalyzed C-H bond activation without the assistance of a directing group. Various arenes such as benzene, toluene, xylene, electron-rich or electron-deficient benzene derivatives, and heteroaromatics are directly carboxylated with high TONs.

Entities: Chemical

Year: 2014 PMID： 25296263 DOI： 10.1039/c4cc06188h

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

7 in total

1. Mechanistic study of the rhodium-catalyzed carboxylation of simple aromatic compounds with carbon dioxide.

Authors: Takuya Suga; Takanobu Saitou; Jun Takaya; Nobuharu Iwasawa
Journal: Chem Sci Date: 2016-11-01 Impact factor: 9.825

2. Formal C-H Carboxylation of Unactivated Arenes.

Authors: Ashot Gevorgyan; Kathrin H Hopmann; Annette Bayer
Journal: Chemistry Date: 2020-05-04 Impact factor: 5.236

3. Photocarboxylation of Benzylic C-H Bonds.

Authors: Qing-Yuan Meng; Tobias E Schirmer; Anna Lucia Berger; Karsten Donabauer; Burkhard König
Journal: J Am Chem Soc Date: 2019-07-11 Impact factor: 15.419

4. Factors Governing the Catalytic Insertion of CO₂ into Arenes - A DFT Case Study for Pd and Pt Phosphane Sulfonamido Complexes.

Authors: Markus Hölscher; Gregor Kemper; Sangeth Jenthra; Carsten Bolm; Walter Leitner
Journal: Chemistry Date: 2022-03-21 Impact factor: 5.020

Direct carboxylation of simple arenes with CO₂ through a rhodium-catalyzed C-H bond activation.

1. Mechanistic study of the rhodium-catalyzed carboxylation of simple aromatic compounds with carbon dioxide.

2. Formal C-H Carboxylation of Unactivated Arenes.

3. Photocarboxylation of Benzylic C-H Bonds.

4. Factors Governing the Catalytic Insertion of CO₂ into Arenes - A DFT Case Study for Pd and Pt Phosphane Sulfonamido Complexes.

Review 5. C-H Carboxylation of Aromatic Compounds through CO₂ Fixation.

6. Direct Photochemical C-H Carboxylation of Aromatic Diamines with CO₂ under Electron-Donor- and Base-free Conditions.

Review 7. Cobalt- and rhodium-catalyzed carboxylation using carbon dioxide as the C1 source.

Direct carboxylation of simple arenes with CO₂ through a rhodium-catalyzed C-H bond activation.

1. Mechanistic study of the rhodium-catalyzed carboxylation of simple aromatic compounds with carbon dioxide.

2. Formal C-H Carboxylation of Unactivated Arenes.

3. Photocarboxylation of Benzylic C-H Bonds.

4. Factors Governing the Catalytic Insertion of CO2 into Arenes - A DFT Case Study for Pd and Pt Phosphane Sulfonamido Complexes.

Review 5. C-H Carboxylation of Aromatic Compounds through CO2 Fixation.

6. Direct Photochemical C-H Carboxylation of Aromatic Diamines with CO2 under Electron-Donor- and Base-free Conditions.

Review 7. Cobalt- and rhodium-catalyzed carboxylation using carbon dioxide as the C1 source.

4. Factors Governing the Catalytic Insertion of CO₂ into Arenes - A DFT Case Study for Pd and Pt Phosphane Sulfonamido Complexes.

Review 5. C-H Carboxylation of Aromatic Compounds through CO₂ Fixation.

6. Direct Photochemical C-H Carboxylation of Aromatic Diamines with CO₂ under Electron-Donor- and Base-free Conditions.