Literature DB >> 25285576

One pot and selective intermolecular aryl- and heteroaryl-trifluoromethylation of alkenes by photoredox catalysis.

Aude Carboni1, Guillaume Dagousset, Emmanuel Magnier, Géraldine Masson.   

Abstract

We report herein the first photoredox-catalyzed intermolecular aryl- and heteroaryltrifluoromethylation of alkenes. Under the optimized conditions using Umemoto's reagent as a CF3 source, a wide range of styrenes can be readily difunctionalized, affording the corresponding trifluoromethylated adducts in up to 99% yield.

Entities:  

Year:  2014        PMID： 25285576     DOI： 10.1039/c4cc07066f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  8 in total

1.  Developments in Photoredox/Nickel Dual-Catalyzed 1,2-Difunctionalizations.

Authors:  Shorouk O Badir; Gary A Molander
Journal:  Chem       Date:  2020-06-11       Impact factor: 22.804

2.  Alkene 1,2-Difunctionalization by Radical Alkenyl Migration.

Authors:  Xinjun Tang; Armido Studer
Journal:  Angew Chem Int Ed Engl       Date:  2017-12-14       Impact factor: 15.336

3.  α-Perfluoroalkyl-β-alkynylation of alkenes via radical alkynyl migration.

Authors:  Xinjun Tang; Armido Studer
Journal:  Chem Sci       Date:  2017-08-04       Impact factor: 9.825

4.  Perfluoroalkylative pyridylation of alkenes via 4-cyanopyridine-boryl radicals.

Authors:  Jia Cao; Guoqiang Wang; Liuzhou Gao; Hui Chen; Xueting Liu; Xu Cheng; Shuhua Li
Journal:  Chem Sci       Date:  2019-01-16       Impact factor: 9.825

5.  Redox-ligand sustains controlled generation of CF3 radicals by well-defined copper complex.

Authors:  Jérémy Jacquet; Sébastien Blanchard; Etienne Derat; Marine Desage-El Murr; Louis Fensterbank
Journal:  Chem Sci       Date:  2015-12-03       Impact factor: 9.825

6.  Additions of Aldehyde-Derived Radicals and Nucleophilic N-Alkylindoles to Styrenes by Photoredox Catalysis.

Authors:  Marcel Lux; Martin Klussmann
Journal:  Org Lett       Date:  2020-04-14       Impact factor: 6.005

7.  Synthesis of Functionalized Cyclopropanes from Carboxylic Acids by a Radical Addition-Polar Cyclization Cascade.

Authors:  Chao Shu; Riccardo S Mega; Björn J Andreassen; Adam Noble; Varinder K Aggarwal
Journal:  Angew Chem Int Ed Engl       Date:  2018-10-25       Impact factor: 15.336

8.  Photoinduced 1,2-dicarbofunctionalization of alkenes with organotrifluoroborate nucleophiles via radical/polar crossover.

Authors:  María Jesús Cabrera-Afonso; Anasheh Sookezian; Shorouk O Badir; Mirna El Khatib; Gary A Molander
Journal:  Chem Sci       Date:  2021-06-07       Impact factor: 9.969
  8 in total

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