Literature DB >> 25283384

Enantioselective iron-catalyzed intramolecular cyclopropanation reactions.

Jun-Jie Shen1, Shou-Fei Zhu, Yan Cai, Huan Xu, Xiu-Lan Xie, Qi-Lin Zhou.   

Abstract

An iron-catalyzed asymmetric intramolecular cyclopropanation was realized in high yields and excellent enantioselectivity (up to 97% ee) by using the iron complexes of chiral spiro-bisoxazoline ligands as catalysts. The superiority of iron catalysts exhibited in this reaction demonstrated the potential abilities of this sustainable metal in asymmetric carbenoid transformation reactions.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  asymmetric catalysis; diazo compounds; iron; small ring systems; spiro compounds

Year:  2014        PMID： 25283384     DOI： 10.1002/anie.201406853

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  10 in total

1.  Further Developments and Applications of Oxazoline-Containing Ligands in Asymmetric Catalysis.

Authors:  Robert Connon; Brendan Roche; Balaji V Rokade; Patrick J Guiry
Journal:  Chem Rev       Date:  2021-05-21       Impact factor: 60.622

2.  Stereodivergent Intramolecular Cyclopropanation Enabled by Engineered Carbene Transferases.

Authors:  Ajay L Chandgude; Xinkun Ren; Rudi Fasan
Journal:  J Am Chem Soc       Date:  2019-05-29       Impact factor: 15.419

3.  Catalytic C(sp3)-H Alkylation via an Iron Carbene Intermediate.

Authors:  Jennifer R Griffin; Chloe I Wendell; Jacob A Garwin; M Christina White
Journal:  J Am Chem Soc       Date:  2017-09-22       Impact factor: 15.419

4.  A Chiral Macrocyclic Tetra-N-Heterocyclic Carbene Yields an "All Carbene" Iron Alkylidene Complex.

Authors:  Joseph F DeJesus; David M Jenkins
Journal:  Chemistry       Date:  2020-01-22       Impact factor: 5.236

5.  Bis(imino)pyridine iron complexes for catalytic carbene transfer reactions.

Authors:  Ban Wang; Isaac G Howard; Jackson W Pope; Eric D Conte; Yongming Deng
Journal:  Chem Sci       Date:  2019-07-02       Impact factor: 9.825

Review 6.  Catalytic enantioselective construction of vicinal quaternary carbon stereocenters.

Authors:  Feng Zhou; Lei Zhu; Bo-Wen Pan; Yang Shi; Yun-Lin Liu; Jian Zhou
Journal:  Chem Sci       Date:  2020-07-28       Impact factor: 9.825

7.  Asymmetric intramolecular α-cyclopropanation of aldehydes using a donor/acceptor carbene mimetic.

Authors:  Chaosheng Luo; Zhen Wang; Yong Huang
Journal:  Nat Commun       Date:  2015-12-08       Impact factor: 14.919

8.  Radical asymmetric intramolecular α-cyclopropanation of aldehydes towards bicyclo[3.1.0]hexanes containing vicinal all-carbon quaternary stereocenters.

Authors:  Liu Ye; Qiang-Shuai Gu; Yu Tian; Xiang Meng; Guo-Cong Chen; Xin-Yuan Liu
Journal:  Nat Commun       Date:  2018-01-15       Impact factor: 14.919

9.  Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation.

Authors:  Meng-Yang Hu; Qiao He; Song-Jie Fan; Zi-Chen Wang; Luo-Yan Liu; Yi-Jiang Mu; Qian Peng; Shou-Fei Zhu
Journal:  Nat Commun       Date:  2018-01-15       Impact factor: 14.919

10.  Blue light-promoted photolysis of aryldiazoacetates.

Authors:  Igor D Jurberg; Huw M L Davies
Journal:  Chem Sci       Date:  2018-05-22       Impact factor: 9.825
  10 in total

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