Literature DB >> 25280006

Palladium-catalyzed oxidative rearrangement of tertiary allylic alcohols to enones with oxygen in aqueous solvent.

Jingjie Li1, Ceheng Tan, Jianxian Gong, Zhen Yang.   

Abstract

A one-pot procedure for Pd(TFA)2-catalyzed 1,3-isomerization of tertiary allylic alcohols to secondary allylic alcohols followed by a Pd(TFA)2/neocuproine-catalyzed oxidative reaction to β-disubstituted-α,β-unsaturated kenones was developed.

Entities:  

Year:  2014        PMID： 25280006     DOI： 10.1021/ol502578h

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Evidence for a Sigmatropic and an Ionic Pathway in the Winstein Rearrangement.

Authors:  Amy A Ott; Mary H Packard; Manuel A Ortuño; Alayna Johnson; Victoria P Suding; Christopher J Cramer; Joseph J Topczewski
Journal:  J Org Chem       Date:  2018-06-14       Impact factor: 4.354

2.  FeCl2-Mediated Rearrangement of Allylic Alcohols.

Authors:  Anita A Oppong-Quaicoe; Brenton DeBoef
Journal:  ACS Omega       Date:  2019-03-29

3.  Late-Stage Chemoenzymatic Installation of Hydroxy-Bearing Allyl Moiety on the Indole Ring of Tryptophan-Containing Peptides.

Authors:  Nagaraju Mupparapu; Lauren Brewster; Katrina F Ostrom; Sherif I Elshahawi
Journal:  Chemistry       Date:  2022-03-10       Impact factor: 5.020
  3 in total

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