| Literature DB >> 25279661 |
Ningning Zhang1, Ran Cheng, Daisy Zhang-Negrerie, Yunfei Du, Kang Zhao.
Abstract
An intramolecular C(sp(3))-O bond formation has been achieved via PhI(OAc)2/NaN3-mediated oxygenation of N,N-diaryl tertiary amines. The appealing features of this method include mild reaction conditions, absence of heavy-metal catalysts, and the direct intramolecular functionalization of sp(3) C-H bonds adjacent to nitrogen.Entities:
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Year: 2014 PMID： 25279661 DOI： 10.1021/jo5016823
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354