Literature DB >> 25268489

Catalytic methylation of aromatic amines with formic acid as the unique carbon and hydrogen source.

Solène Savourey1, Guillaume Lefèvre, Jean-Claude Berthet, Thibault Cantat.   

Abstract

A novel methodology is presented for the direct methylation of amines, using formic acid as a unique source of carbon and hydrogen. Based on ruthenium(II) catalysts, the formation of the N-CH3 group proceeds via an efficient formylation/transfer hydrogenation pathway.

Entities:  

Year:  2014        PMID： 25268489     DOI： 10.1039/c4cc05908e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  A versatile way for the synthesis of monomethylamines by reduction of N-substituted carbonylimidazoles with the NaBH4/I2 system.

Authors:  Lin Chen; Xuan Zhou; Zhiyong Chen; Changxu Wang; Shunjie Wang; Hanbing Teng
Journal:  Beilstein J Org Chem       Date:  2022-08-17       Impact factor: 2.544

2.  Cobalt-catalysed reductive C-H alkylation of indoles using carboxylic acids and molecular hydrogen.

Authors:  Jose R Cabrero-Antonino; Rosa Adam; Kathrin Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-07-26       Impact factor: 9.825

3.  Unprecedented selective homogeneous cobalt-catalysed reductive alkoxylation of cyclic imides under mild conditions.

Authors:  Jose R Cabrero-Antonino; Rosa Adam; Veronica Papa; Mattes Holsten; Kathrin Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-06-12       Impact factor: 9.825

4.  Metal-free disproportionation of formic acid mediated by organoboranes.

Authors:  Clément Chauvier; Pierre Thuéry; Thibault Cantat
Journal:  Chem Sci       Date:  2016-05-19       Impact factor: 9.825

5.  Towards a general ruthenium-catalyzed hydrogenation of secondary and tertiary amides to amines.

Authors:  Jose R Cabrero-Antonino; Elisabetta Alberico; Kathrin Junge; Henrik Junge; Matthias Beller
Journal:  Chem Sci       Date:  2016-02-09       Impact factor: 9.825
  5 in total

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