Literature DB >> 25264941

Small-molecule "BRCA1-mimetics" are antagonists of estrogen receptor-α.

Yongxian Ma1, York Tomita, Anju Preet, Robert Clarke, Erikah Englund, Scott Grindrod, Shyam Nathan, Eliseu De Oliveira, Milton L Brown, Eliot M Rosen.   

Abstract

CONTEXT: Resistance to conventional antiestrogens is a major cause of treatment failure and, ultimately, death in breast cancer.
OBJECTIVE: The objective of the study was to identify small-molecule estrogen receptor (ER)-α antagonists that work differently from tamoxifen and other selective estrogen receptor modulators.
DESIGN: Based on in silico screening of a pharmacophore database using a computed model of the BRCA1-ER-α complex (with ER-α liganded to 17β-estradiol), we identified a candidate group of small-molecule compounds predicted to bind to a BRCA1-binding interface separate from the ligand-binding pocket and the coactivator binding site of ER-α. Among 40 candidate compounds, six inhibited estradiol-stimulated ER-α activity by at least 50% in breast carcinoma cells, with IC50 values ranging between 3 and 50 μM. These ER-α inhibitory compounds were further studied by molecular and cell biological techniques.
RESULTS: The compounds strongly inhibited ER-α activity at concentrations that yielded little or no nonspecific toxicity, but they produced only a modest inhibition of progesterone receptor activity. Importantly, the compounds blocked proliferation and inhibited ER-α activity about equally well in antiestrogen-sensitive and antiestrogen-resistant breast cancer cells. Representative compounds disrupted the interaction of BRCA1 and ER-α in the cultured cells and blocked the interaction of ER-α with the estrogen response element. However, the compounds had no effect on the total cellular ER-α levels.
CONCLUSIONS: These findings suggest that we have identified a new class of ER-α antagonists that work differently from conventional antiestrogens (eg, tamoxifen and fulvestrant).

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Year:  2014        PMID: 25264941      PMCID: PMC4250363          DOI: 10.1210/me.2014-1146

Source DB:  PubMed          Journal:  Mol Endocrinol        ISSN: 0888-8809


  46 in total

1.  The RING heterodimer BRCA1-BARD1 is a ubiquitin ligase inactivated by a breast cancer-derived mutation.

Authors:  R Hashizume; M Fukuda; I Maeda; H Nishikawa; D Oyake; Y Yabuki; H Ogata; T Ohta
Journal:  J Biol Chem       Date:  2001-03-06       Impact factor: 5.157

2.  Role of direct interaction in BRCA1 inhibition of estrogen receptor activity.

Authors:  S Fan; Y X Ma; C Wang; R Q Yuan; Q Meng; J A Wang; M Erdos; I D Goldberg; P Webb; P J Kushner; R G Pestell; E M Rosen
Journal:  Oncogene       Date:  2001-01-04       Impact factor: 9.867

3.  Structure of a BRCA1-BARD1 heterodimeric RING-RING complex.

Authors:  P S Brzovic; P Rajagopal; D W Hoyt; M C King; R E Klevit
Journal:  Nat Struct Biol       Date:  2001-10

4.  Cancer-predisposing mutations within the RING domain of BRCA1: loss of ubiquitin protein ligase activity and protection from radiation hypersensitivity.

Authors:  H Ruffner; C A Joazeiro; D Hemmati; T Hunter; I M Verma
Journal:  Proc Natl Acad Sci U S A       Date:  2001-04-24       Impact factor: 11.205

5.  Identification of a second binding site in the estrogen receptor.

Authors:  Willem P van Hoorn
Journal:  J Med Chem       Date:  2002-01-31       Impact factor: 7.446

6.  Transcriptional synergism on the pS2 gene promoter between a p160 coactivator and estrogen receptor-alpha depends on the coactivator subtype, the type of estrogen response element, and the promoter context.

Authors:  Tomas Barkhem; Lars-Arne Haldosén; Jan-Ake Gustafsson; Stefan Nilsson
Journal:  Mol Endocrinol       Date:  2002-11

7.  Transcriptional activation of cathepsin D gene expression by 17beta-estradiol: mechanism of aryl hydrocarbon receptor-mediated inhibition.

Authors:  F Wang; I Samudio; S Safe
Journal:  Mol Cell Endocrinol       Date:  2001-02-14       Impact factor: 4.102

8.  Cancer Incidence in BRCA1 mutation carriers.

Authors:  Deborah Thompson; Douglas F Easton
Journal:  J Natl Cancer Inst       Date:  2002-09-18       Impact factor: 13.506

9.  Haplo-insufficiency of BRCA1 in sporadic breast cancer.

Authors:  Synnöve Staff; Jorma Isola; Minna Tanner
Journal:  Cancer Res       Date:  2003-08-15       Impact factor: 12.701

Review 10.  A review of selective estrogen receptor modulators and national surgical adjuvant breast and bowel project clinical trials.

Authors:  Roy E Smith
Journal:  Semin Oncol       Date:  2003-10       Impact factor: 4.929

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  3 in total

1.  BRCA1-mimetic compound NSC35446.HCl inhibits IKKB expression by reducing estrogen receptor-α occupancy in the IKKB promoter and inhibits NF-κB activity in antiestrogen-resistant human breast cancer cells.

Authors:  Shyam Nathan; Yongxian Ma; York A Tomita; Eliseu De Oliveira; Milton L Brown; Eliot M Rosen
Journal:  Breast Cancer Res Treat       Date:  2017-08-14       Impact factor: 4.872

Review 2.  Update on the Role of NFκB in Promoting Aggressive Phenotypes of Estrogen Receptor-Positive Breast Cancer.

Authors:  Emily Smart; Svetlana E Semina; Jonna Frasor
Journal:  Endocrinology       Date:  2020-10-01       Impact factor: 4.736

3.  A new class of small molecule estrogen receptor-alpha antagonists that overcome anti-estrogen resistance.

Authors:  Yongxian Ma; Anju Preet; York Tomita; Eliseu De Oliveira; Li Zhang; Yumi Ueda; Robert Clarke; Milton Brown; Eliot M Rosen
Journal:  Oncotarget       Date:  2015-12-01
  3 in total

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