Peach gum polysaccharide polyelectrolyte: preparation, properties and application in layer-by-layer self-assembly.

The hydrolyzed peach gum polysaccharide (HPGP) prepared at acidic condition is investigated as an anionic polyelectrolyte for the first time. A hydrolysis mechanism is proposed by monitoring the hydrolysis efficiency and morphological change of crude peach gum, and the intrinsic viscosity of resulted HPGP as a function of hydrolysis time. Fourier transform infrared (FTIR) spectroscopy and ζ-potential measurements reveal that HPGP with multiple carboxylic groups is negatively charged in water in the pH range 3-11. The HPGP exhibits remarkable pH and ionic strength responsiveness, as proven by dynamic light scattering (DLS) and atomic force microscopy (AFM) measurements. Moreover, the layer-by-layer (LbL) self-assembly experiments further confirmed that the HPGP can be utilized as an anionic polyelectrolyte. Considering the facile availability, favorable compatibility and intriguing functionality of HPGP, this study opens up enormous opportunities for the large-scale utilization of peach gum resource.