Literature DB >> 25256121

Synthesis of chlorosilicates.

Simon Steinhauer1, Tobias Böttcher, Nico Schwarze, Beate Neumann, Hans-Georg Stammler, Berthold Hoge.   

Abstract

Chlorosilicates represent important intermediates in S(N)2 reactions of chlorosilanes. They can be stabilized by the introduction of electron-withdrawing substituents. Salts of various (pentafluoroethyl)chlorosilicates have been isolated and structurally characterized.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  Lewis acids; electron-withdrawing groups; nucleophilic substitution; silicates; solvent effects

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Year:  2014        PMID： 25256121     DOI： 10.1002/anie.201406311

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  Bis(perfluoropinacolato)silane: A Neutral Silane Lewis Superacid Activates Si-F Bonds.

Authors:  Florian S Tschernuth; Thaddäus Thorwart; Lutz Greb; Franziska Hanusch; Shigeyoshi Inoue
Journal:  Angew Chem Int Ed Engl       Date:  2021-11-05       Impact factor: 16.823

2.  Bis(catecholato)silanes: assessing, rationalizing and increasing silicon's Lewis superacidity.

Authors:  Deborah Hartmann; Marcel Schädler; Lutz Greb
Journal:  Chem Sci       Date:  2019-06-17       Impact factor: 9.825

3.  Synthesis and Characterization of Hypercoordinated Silicon Anions: Catching Intermediates of Lewis Base Catalysis.

Authors:  Nils Ansmann; Deborah Hartmann; Sonja Sailer; Philipp Erdmann; Rezisha Maskey; Marcel Schorpp; Lutz Greb
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-05       Impact factor: 16.823

4.  Oxidative Additions of C-F Bonds to the Silanide Anion [Si(C2 F5 )3 ].

Authors:  Natalia Tiessen; Mira Keßler; Beate Neumann; Hans-Georg Stammler; Berthold Hoge
Journal:  Angew Chem Int Ed Engl       Date:  2022-02-28       Impact factor: 16.823
  4 in total

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