Literature DB >> 25250790

Functionalization of P4 using a Lewis acid stabilized bicyclo[1.1.0]tetraphosphabutane anion.

Jaap E Borger1, Andreas W Ehlers, Martin Lutz, J Chris Slootweg, Koop Lammertsma.   

Abstract

Reacting white phosphorus (P4 ) with sterically encumbered aryl lithium reagents (aryl=2,6-dimesitylphenyl or 2,4,6-tBu3 C6 H2 ) and B(C6 F5 )3 gives the unique, isolable Lewis acid stabilized bicyclo[1.1.0]tetraphosphabutane anion. Subsequent alkylation of the nucleophilic site of the RP4 anion gives access to non-symmetrical disubstituted bicyclic tetraphosphorus compounds. This novel method enables PC bond formation in a controlled fashion using white phosphorus as starting material.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  alkali metals; anions; nucleophilic addition; phosphorus; white phosphorus

Mesh：

Substances：

Year:  2014        PMID： 25250790     DOI： 10.1002/anie.201405879

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  8 in total

1.  Attenuated Organomagnesium Activation of White Phosphorus.

Authors:  Merle Arrowsmith; Michael S Hill; Andrew L Johnson; Gabriele Kociok-Köhn; Mary F Mahon
Journal:  Angew Chem Int Ed Engl       Date:  2015-05-27       Impact factor: 15.336

2.  Metalate-Mediated Functionalization of P4 by Trapping Anionic [Cp*Fe(CO)2(η1-P4)]- with Lewis Acids.

Authors:  Jaap E Borger; Maarten K Jongkind; Andreas W Ehlers; Martin Lutz; J Chris Slootweg; Koop Lammertsma
Journal:  ChemistryOpen       Date:  2017-03-23       Impact factor: 2.911

Review 3.  Functionalization of P4 through Direct P-C Bond Formation.

Authors:  Jaap E Borger; Andreas W Ehlers; J Chris Slootweg; Koop Lammertsma
Journal:  Chemistry       Date:  2017-07-27       Impact factor: 5.236

Review 4.  Functionalization of Pentaphosphorus Cations by Complexation.

Authors:  Anup K Adhikari; Christoph G P Ziegler; Kai Schwedtmann; Clemens Taube; Jan J Weigand; Robert Wolf
Journal:  Angew Chem Int Ed Engl       Date:  2019-11-06       Impact factor: 15.336

5.  First experimental evidence for the elusive tetrahedral cations [EP3]+ (E = S, Se, Te) in the condensed phase.

Authors:  Philippe Weis; David Christopher Röhner; Richard Prediger; Burkhard Butschke; Harald Scherer; Stefan Weber; Ingo Krossing
Journal:  Chem Sci       Date:  2019-10-07       Impact factor: 9.825

6.  Binding, Release and Functionalization of Intact Pnictogen Tetrahedra Coordinated to Dicopper Complexes.

Authors:  Martin Piesch; Amélie Nicolay; Maria Haimerl; Michael Seidl; Gábor Balázs; T Don Tilley; Manfred Scheer
Journal:  Chemistry       Date:  2022-06-23       Impact factor: 5.020

7.  [P4H]+[Al(OTeF5)4]-: protonation of white phosphorus with the Brønsted superacid H[Al(OTeF5)4](solv).

Authors:  Anja Wiesner; Simon Steinhauer; Helmut Beckers; Christian Müller; Sebastian Riedel
Journal:  Chem Sci       Date:  2018-08-23       Impact factor: 9.825

8.  Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1,2,3-triphosphol-2-ides.

Authors:  Dennis Rottschäfer; Sebastian Blomeyer; Beate Neumann; Hans-Georg Stammler; Rajendra S Ghadwal
Journal:  Chem Sci       Date:  2019-10-18       Impact factor: 9.825
  8 in total

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