1-[3-(Morpholin-4-yl)prop-yl]-3-[(naph-tha-len-2-yl)oxy]-4-(3-nitro-phen-yl)azeti-din-2-one.

In the title compound, C26H27N3O5, the β-lactam (azetidin-2-one) ring is nearly planar [maximum deviation = 0.011 (3) Å]. The mean plane formed by the four C atoms of the morpholine ring, which adopts a chair conformation, the benzene ring and the naphthalene ring system form dihedral angles of 72.85 (17), 87.46 (15) and 65.96 (11)°, respectively, with the β-lactam ring. In the crystal, molecules are linked via C-H⋯O hydrogen bonds, forming inversion dimers with R 2 (2)(8).

Related literature

For general background to β-lactams, see: Mehta et al. (2010 ▶); Arumugam et al. (2011 ▶); Myangar & Raval (2012 ▶); Singh & Sudheesh (2014 ▶); Abdellaoui & Xu (2014 ▶); Cheng & Cheng (2007 ▶); Xiang (2013 ▶). For ring-puckering parameters, see: Cremer & Pople (1975 ▶). For hydrogen-bond motifs, see: Bernstein et al. (1995 ▶).

Experimental

Crystal data

C26H27N3O5

M = 461.51

Triclinic,

a = 9.7068 (8) Å

b = 10.3836 (9) Å

c = 14.2041 (11) Å

α = 73.739 (6)°

β = 75.922 (6)°

γ = 63.107 (6)°

V = 1214.33 (19) Å3

Z = 2

Mo Kα radiation

μ = 0.09 mm−1

T = 296 K

0.51 × 0.39 × 0.25 mm

Data collection

Stoe IPDS 2 diffractometer

Absorption correction: integration (X-RED32; Stoe & Cie, 2002 ▶) T min = 0.967, T max = 0.985

10059 measured reflections

4486 independent reflections

2123 reflections with I > 2σ(I)

R int = 0.088

Refinement

R[F 2 > 2σ(F 2)] = 0.066

wR(F 2) = 0.176

S = 0.95

4486 reflections

307 parameters

H-atom parameters constrained

Δρmax = 0.28 e Å−3

Δρmin = −0.17 e Å−3

Data collection: X-AREA (Stoe & Cie, 2002 ▶); cell refinement: X-AREA; data reduction: X-RED32 (Stoe & Cie, 2002 ▶); program(s) used to solve structure: SHELXS2013 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL2013 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 for Windows (Farrugia, 2012 ▶); software used to prepare material for publication: WinGX (Farrugia, 2012 ▶).

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536814014949/hg5396sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536814014949/hg5396Isup2.hkl

Click here for additional data file.

Supporting information file. DOI: 10.1107/S1600536814014949/hg5396Isup3.cml

CCDC reference: 1010107

Additional supporting information: crystallographic information; 3D view; checkCIF report

C26H27N3O5	Z = 2
Mr = 461.51	F(000) = 488
Triclinic, P1	Dx = 1.262 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 9.7068 (8) Å	Cell parameters from 9755 reflections
b = 10.3836 (9) Å	θ = 1.5–28.8°
c = 14.2041 (11) Å	µ = 0.09 mm−1
α = 73.739 (6)°	T = 296 K
β = 75.922 (6)°	Block, light yellow
γ = 63.107 (6)°	0.51 × 0.39 × 0.25 mm
V = 1214.33 (19) Å3

Stoe IPDS 2 diffractometer	4486 independent reflections
Radiation source: sealed X-ray tube, 12 x 0.4 mm long-fine focus	2123 reflections with I > 2σ(I)
Plane graphite monochromator	Rint = 0.088
Detector resolution: 6.67 pixels mm-1	θmax = 25.5°, θmin = 2.2°
ω scans	h = −11→11
Absorption correction: integration (X-RED32; Stoe & Cie, 2002)	k = −12→12
Tmin = 0.967, Tmax = 0.985	l = −17→16
10059 measured reflections

Refinement on F2	0 restraints
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.066	H-atom parameters constrained
wR(F2) = 0.176	w = 1/[σ2(Fo2) + (0.0805P)2] where P = (Fo2 + 2Fc2)/3
S = 0.95	(Δ/σ)max < 0.001
4486 reflections	Δρmax = 0.28 e Å−3
307 parameters	Δρmin = −0.17 e Å−3

Geometry. Bond distances, angles etc. have been calculated using the rounded fractional coordinates. All su's are estimated from the variances of the (full) variance-covariance matrix. The cell e.s.d.'s are taken into account in the estimation of distances, angles and torsion angles

Refinement. Refinement on F2 for ALL reflections except those flagged by the user for potential systematic errors. Weighted R-factors wR and all goodnesses of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The observed criterion of F2 > σ(F2) is used only for calculating -R-factor-obs etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R-factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
O1	0.9297 (3)	1.1424 (3)	0.07366 (17)	0.0961 (10)
O2	0.7976 (2)	0.9168 (2)	0.21877 (14)	0.0753 (8)
O3	0.8014 (5)	1.0509 (4)	0.4976 (2)	0.1465 (14)
O4	0.8408 (5)	0.8838 (4)	0.6243 (2)	0.172 (2)
O5	1.7676 (3)	0.5318 (3)	−0.1356 (2)	0.1070 (11)
N1	1.1173 (3)	0.9410 (3)	0.16271 (17)	0.0677 (10)
N2	0.8603 (5)	0.9237 (5)	0.5366 (2)	0.1089 (15)
N3	1.5567 (3)	0.7649 (3)	−0.03474 (17)	0.0658 (9)
C1	0.9845 (4)	1.0180 (4)	0.1211 (2)	0.0716 (11)
C2	0.9402 (4)	0.8877 (4)	0.1546 (2)	0.0711 (11)
C3	1.0932 (4)	0.8057 (3)	0.2041 (2)	0.0657 (11)
C4	0.7483 (4)	0.8039 (4)	0.2538 (2)	0.0679 (11)
C5	0.6102 (4)	0.8383 (4)	0.3220 (2)	0.0810 (11)
C6	0.5486 (4)	0.7382 (5)	0.3597 (2)	0.0852 (14)
C7	0.6183 (4)	0.5988 (4)	0.3316 (2)	0.0779 (13)
C8	0.5543 (5)	0.4935 (6)	0.3687 (3)	0.0995 (18)
C9	0.6232 (6)	0.3623 (6)	0.3379 (4)	0.114 (2)
C10	0.7574 (6)	0.3308 (5)	0.2710 (3)	0.1057 (19)
C11	0.8243 (5)	0.4271 (4)	0.2350 (3)	0.0871 (16)
C12	0.7571 (4)	0.5656 (4)	0.2643 (2)	0.0723 (11)
C13	0.8214 (4)	0.6705 (4)	0.2268 (2)	0.0715 (11)
C14	1.0772 (3)	0.7610 (3)	0.3149 (2)	0.0618 (10)
C15	0.9834 (4)	0.8625 (3)	0.3742 (2)	0.0703 (11)
C16	0.9656 (4)	0.8152 (4)	0.4753 (2)	0.0739 (11)
C17	1.0402 (5)	0.6725 (4)	0.5206 (3)	0.0847 (15)
C18	1.1351 (4)	0.5718 (4)	0.4615 (3)	0.0848 (14)
C19	1.1519 (4)	0.6162 (4)	0.3600 (2)	0.0763 (12)
C20	1.2491 (4)	0.9733 (4)	0.1582 (2)	0.0791 (14)
C21	1.4021 (4)	0.8613 (4)	0.1168 (2)	0.0746 (11)
C22	1.4024 (4)	0.8513 (4)	0.0131 (2)	0.0718 (11)
C23	1.6225 (4)	0.6141 (4)	0.0167 (3)	0.0847 (14)
C24	1.7765 (5)	0.5274 (4)	−0.0364 (3)	0.1093 (17)
C25	1.7052 (5)	0.6771 (4)	−0.1862 (3)	0.1020 (16)
C26	1.5468 (4)	0.7661 (4)	−0.1358 (2)	0.0847 (13)
H2	0.94510	0.84580	0.09940	0.0850*
H3	1.17070	0.72420	0.17220	0.0790*
H5	0.56200	0.92930	0.34080	0.0970*
H6	0.45820	0.76100	0.40520	0.1030*
H8	0.46420	0.51380	0.41450	0.1190*
H9	0.57950	0.29410	0.36210	0.1370*
H10	0.80300	0.24130	0.25030	0.1270*
H11	0.91550	0.40250	0.19030	0.1040*
H13	0.91410	0.64830	0.18340	0.0860*
H15	0.93290	0.96150	0.34630	0.0850*
H17	1.02720	0.64410	0.58910	0.1010*
H18	1.18800	0.47360	0.49010	0.1020*
H19	1.21530	0.54660	0.32100	0.0910*
H20A	1.25690	0.97640	0.22430	0.0950*
H20B	1.23130	1.07000	0.11720	0.0950*
H21A	1.48590	0.88780	0.11710	0.0890*
H21B	1.42240	0.76530	0.15940	0.0890*
H22A	1.33220	0.80730	0.01490	0.0860*
H22B	1.36270	0.95000	−0.02650	0.0860*
H23A	1.55120	0.56930	0.02280	0.1020*
H23B	1.63540	0.61160	0.08290	0.1020*
H24A	1.85050	0.56620	−0.03630	0.1310*
H24B	1.81480	0.42580	−0.00120	0.1310*
H25A	1.69630	0.67850	−0.25300	0.1220*
H25B	1.77550	0.72220	−0.19050	0.1220*
H26A	1.50790	0.86680	−0.17250	0.1010*
H26B	1.47430	0.72500	−0.13480	0.1010*

	U11	U22	U33	U12	U13	U23
O1	0.112 (2)	0.0782 (16)	0.0649 (14)	−0.0169 (14)	−0.0123 (13)	−0.0032 (12)
O2	0.0629 (14)	0.0846 (15)	0.0576 (12)	−0.0106 (12)	−0.0013 (10)	−0.0233 (11)
O3	0.178 (3)	0.114 (2)	0.082 (2)	−0.006 (2)	0.015 (2)	−0.0443 (18)
O4	0.246 (5)	0.162 (3)	0.0539 (17)	−0.057 (3)	0.026 (2)	−0.0303 (17)
O5	0.124 (2)	0.0752 (17)	0.0928 (19)	−0.0129 (15)	0.0003 (16)	−0.0356 (14)
N1	0.0710 (19)	0.0701 (16)	0.0528 (14)	−0.0232 (15)	0.0043 (13)	−0.0197 (12)
N2	0.136 (3)	0.110 (3)	0.0547 (19)	−0.033 (2)	0.0065 (18)	−0.0251 (17)
N3	0.0670 (17)	0.0656 (16)	0.0528 (13)	−0.0176 (12)	−0.0016 (12)	−0.0164 (11)
C1	0.084 (2)	0.074 (2)	0.0428 (15)	−0.0215 (19)	−0.0004 (16)	−0.0171 (15)
C2	0.071 (2)	0.086 (2)	0.0449 (15)	−0.0215 (17)	0.0014 (15)	−0.0230 (15)
C3	0.065 (2)	0.0658 (19)	0.0536 (16)	−0.0155 (15)	0.0038 (14)	−0.0231 (14)
C4	0.058 (2)	0.084 (2)	0.0472 (15)	−0.0167 (18)	−0.0084 (14)	−0.0122 (15)
C5	0.062 (2)	0.092 (2)	0.0609 (19)	−0.0081 (19)	0.0021 (16)	−0.0233 (17)
C6	0.059 (2)	0.115 (3)	0.0569 (19)	−0.020 (2)	0.0055 (16)	−0.0194 (19)
C7	0.060 (2)	0.105 (3)	0.0532 (18)	−0.022 (2)	−0.0069 (16)	−0.0142 (18)
C8	0.080 (3)	0.129 (4)	0.080 (2)	−0.040 (3)	−0.005 (2)	−0.017 (3)
C9	0.123 (4)	0.126 (4)	0.099 (3)	−0.059 (3)	−0.021 (3)	−0.012 (3)
C10	0.118 (4)	0.099 (3)	0.093 (3)	−0.039 (3)	−0.017 (3)	−0.016 (2)
C11	0.085 (3)	0.090 (3)	0.068 (2)	−0.019 (2)	−0.0080 (18)	−0.0204 (19)
C12	0.060 (2)	0.091 (2)	0.0507 (16)	−0.0171 (18)	−0.0105 (15)	−0.0134 (16)
C13	0.0550 (19)	0.087 (2)	0.0537 (17)	−0.0114 (18)	−0.0009 (14)	−0.0228 (16)
C14	0.0565 (18)	0.0656 (19)	0.0569 (16)	−0.0184 (15)	−0.0073 (14)	−0.0149 (14)
C15	0.082 (2)	0.0648 (19)	0.0496 (16)	−0.0171 (16)	−0.0044 (15)	−0.0167 (13)
C16	0.088 (2)	0.081 (2)	0.0501 (17)	−0.0328 (19)	−0.0065 (16)	−0.0150 (16)
C17	0.100 (3)	0.096 (3)	0.0556 (18)	−0.043 (2)	−0.0189 (19)	0.0003 (19)
C18	0.090 (3)	0.072 (2)	0.082 (2)	−0.029 (2)	−0.029 (2)	0.0073 (19)
C19	0.073 (2)	0.069 (2)	0.075 (2)	−0.0176 (17)	−0.0127 (17)	−0.0144 (16)
C20	0.092 (3)	0.086 (2)	0.0628 (19)	−0.036 (2)	0.0025 (17)	−0.0324 (16)
C21	0.074 (2)	0.097 (2)	0.0592 (18)	−0.0372 (19)	−0.0003 (16)	−0.0291 (16)
C22	0.065 (2)	0.086 (2)	0.0564 (17)	−0.0224 (17)	−0.0041 (15)	−0.0211 (15)
C23	0.094 (3)	0.076 (2)	0.070 (2)	−0.022 (2)	−0.0124 (19)	−0.0149 (17)
C24	0.108 (3)	0.080 (3)	0.103 (3)	−0.003 (2)	−0.017 (2)	−0.023 (2)
C25	0.123 (3)	0.085 (3)	0.071 (2)	−0.024 (2)	0.013 (2)	−0.0307 (19)
C26	0.095 (3)	0.082 (2)	0.0551 (18)	−0.0142 (19)	−0.0082 (17)	−0.0212 (15)

O1—C1	1.213 (4)	C18—C19	1.378 (5)
O2—C2	1.414 (4)	C20—C21	1.516 (5)
O2—C4	1.384 (4)	C21—C22	1.505 (4)
O3—N2	1.200 (6)	C23—C24	1.493 (6)
O4—N2	1.194 (4)	C25—C26	1.510 (6)
O5—C24	1.419 (5)	C2—H2	0.9800
O5—C25	1.392 (5)	C3—H3	0.9800
N1—C1	1.351 (5)	C5—H5	0.9300
N1—C3	1.464 (4)	C6—H6	0.9300
N1—C20	1.446 (5)	C8—H8	0.9300
N2—C16	1.465 (5)	C9—H9	0.9300
N3—C22	1.463 (5)	C10—H10	0.9300
N3—C23	1.441 (5)	C11—H11	0.9300
N3—C26	1.458 (4)	C13—H13	0.9300
C1—C2	1.519 (6)	C15—H15	0.9300
C2—C3	1.566 (6)	C17—H17	0.9300
C3—C14	1.501 (4)	C18—H18	0.9300
C4—C5	1.411 (5)	C19—H19	0.9300
C4—C13	1.358 (5)	C20—H20A	0.9700
C5—C6	1.349 (6)	C20—H20B	0.9700
C6—C7	1.421 (6)	C21—H21A	0.9700
C7—C8	1.411 (7)	C21—H21B	0.9700
C7—C12	1.409 (5)	C22—H22A	0.9700
C8—C9	1.365 (8)	C22—H22B	0.9700
C9—C10	1.376 (8)	C23—H23A	0.9700
C10—C11	1.350 (7)	C23—H23B	0.9700
C11—C12	1.422 (5)	C24—H24A	0.9700
C12—C13	1.410 (6)	C24—H24B	0.9700
C14—C15	1.380 (4)	C25—H25A	0.9700
C14—C19	1.377 (5)	C25—H25B	0.9700
C15—C16	1.376 (4)	C26—H26A	0.9700
C16—C17	1.362 (5)	C26—H26B	0.9700
C17—C18	1.375 (6)
C2—O2—C4	117.4 (3)	C14—C3—H3	112.00
C24—O5—C25	110.2 (3)	C4—C5—H5	120.00
C1—N1—C3	96.4 (3)	C6—C5—H5	120.00
C1—N1—C20	132.1 (3)	C5—C6—H6	119.00
C3—N1—C20	131.1 (3)	C7—C6—H6	119.00
O3—N2—O4	121.9 (4)	C7—C8—H8	120.00
O3—N2—C16	119.0 (3)	C9—C8—H8	120.00
O4—N2—C16	119.0 (4)	C8—C9—H9	120.00
C22—N3—C23	112.9 (3)	C10—C9—H9	120.00
C22—N3—C26	109.7 (3)	C9—C10—H10	119.00
C23—N3—C26	108.5 (3)	C11—C10—H10	119.00
O1—C1—N1	131.9 (4)	C10—C11—H11	119.00
O1—C1—C2	136.2 (4)	C12—C11—H11	120.00
N1—C1—C2	91.9 (3)	C4—C13—H13	120.00
O2—C2—C1	113.2 (3)	C12—C13—H13	120.00
O2—C2—C3	116.9 (2)	C14—C15—H15	121.00
C1—C2—C3	85.7 (3)	C16—C15—H15	120.00
N1—C3—C2	85.9 (2)	C16—C17—H17	121.00
N1—C3—C14	115.7 (3)	C18—C17—H17	121.00
C2—C3—C14	117.7 (3)	C17—C18—H18	120.00
O2—C4—C5	114.0 (3)	C19—C18—H18	120.00
O2—C4—C13	125.1 (3)	C14—C19—H19	119.00
C5—C4—C13	120.9 (4)	C18—C19—H19	119.00
C4—C5—C6	119.6 (4)	N1—C20—H20A	109.00
C5—C6—C7	121.6 (4)	N1—C20—H20B	109.00
C6—C7—C8	122.6 (4)	C21—C20—H20A	109.00
C6—C7—C12	118.1 (4)	C21—C20—H20B	109.00
C8—C7—C12	119.3 (4)	H20A—C20—H20B	108.00
C7—C8—C9	120.6 (5)	C20—C21—H21A	109.00
C8—C9—C10	120.1 (5)	C20—C21—H21B	109.00
C9—C10—C11	121.4 (5)	C22—C21—H21A	109.00
C10—C11—C12	120.9 (4)	C22—C21—H21B	109.00
C7—C12—C11	117.7 (4)	H21A—C21—H21B	108.00
C7—C12—C13	119.6 (3)	N3—C22—H22A	109.00
C11—C12—C13	122.7 (4)	N3—C22—H22B	109.00
C4—C13—C12	120.2 (3)	C21—C22—H22A	109.00
C3—C14—C15	121.1 (3)	C21—C22—H22B	109.00
C3—C14—C19	120.7 (3)	H22A—C22—H22B	108.00
C15—C14—C19	118.2 (3)	N3—C23—H23A	109.00
C14—C15—C16	119.1 (3)	N3—C23—H23B	109.00
N2—C16—C15	118.2 (3)	C24—C23—H23A	109.00
N2—C16—C17	118.8 (3)	C24—C23—H23B	109.00
C15—C16—C17	123.1 (3)	H23A—C23—H23B	108.00
C16—C17—C18	117.8 (4)	O5—C24—H24A	109.00
C17—C18—C19	120.1 (4)	O5—C24—H24B	109.00
C14—C19—C18	121.7 (3)	C23—C24—H24A	109.00
N1—C20—C21	113.1 (3)	C23—C24—H24B	109.00
C20—C21—C22	112.8 (3)	H24A—C24—H24B	108.00
N3—C22—C21	113.6 (3)	O5—C25—H25A	109.00
N3—C23—C24	111.5 (3)	O5—C25—H25B	109.00
O5—C24—C23	112.4 (4)	C26—C25—H25A	109.00
O5—C25—C26	112.0 (3)	C26—C25—H25B	109.00
N3—C26—C25	110.4 (3)	H25A—C25—H25B	108.00
O2—C2—H2	113.00	N3—C26—H26A	109.00
C1—C2—H2	113.00	N3—C26—H26B	110.00
C3—C2—H2	113.00	C25—C26—H26A	110.00
N1—C3—H3	112.00	C25—C26—H26B	110.00
C2—C3—H3	112.00	H26A—C26—H26B	108.00
C2—O2—C4—C5	176.4 (3)	C2—C3—C14—C15	−54.0 (5)
C4—O2—C2—C1	−179.5 (3)	N1—C3—C14—C19	−136.8 (4)
C4—O2—C2—C3	−82.2 (4)	O2—C4—C13—C12	−177.4 (3)
C2—O2—C4—C13	−4.1 (5)	C5—C4—C13—C12	2.1 (5)
C25—O5—C24—C23	55.7 (5)	C13—C4—C5—C6	−1.1 (5)
C24—O5—C25—C26	−56.8 (5)	O2—C4—C5—C6	178.5 (3)
C20—N1—C1—C2	171.6 (3)	C4—C5—C6—C7	−0.8 (5)
C3—N1—C1—O1	179.9 (4)	C5—C6—C7—C12	1.5 (5)
C20—N1—C1—O1	−6.8 (6)	C5—C6—C7—C8	−178.8 (4)
C3—N1—C20—C21	50.6 (4)	C12—C7—C8—C9	−1.8 (7)
C20—N1—C3—C14	69.3 (4)	C8—C7—C12—C13	179.9 (4)
C1—N1—C3—C2	1.7 (2)	C6—C7—C8—C9	178.5 (4)
C1—N1—C20—C21	−120.6 (4)	C6—C7—C12—C11	−178.7 (3)
C3—N1—C1—C2	−1.7 (2)	C6—C7—C12—C13	−0.4 (5)
C1—N1—C3—C14	−117.2 (3)	C8—C7—C12—C11	1.5 (5)
C20—N1—C3—C2	−171.8 (3)	C7—C8—C9—C10	0.8 (8)
O3—N2—C16—C17	175.7 (5)	C8—C9—C10—C11	0.5 (8)
O4—N2—C16—C17	−1.2 (8)	C9—C10—C11—C12	−0.7 (7)
O3—N2—C16—C15	−4.8 (7)	C10—C11—C12—C7	−0.3 (6)
O4—N2—C16—C15	178.3 (5)	C10—C11—C12—C13	−178.6 (4)
C26—N3—C22—C21	−177.8 (3)	C7—C12—C13—C4	−1.4 (5)
C23—N3—C26—C25	−56.2 (4)	C11—C12—C13—C4	176.9 (4)
C22—N3—C26—C25	−179.9 (3)	C3—C14—C19—C18	−178.0 (4)
C22—N3—C23—C24	177.4 (3)	C19—C14—C15—C16	−1.3 (6)
C26—N3—C23—C24	55.6 (4)	C3—C14—C15—C16	176.5 (4)
C23—N3—C22—C21	61.1 (4)	C15—C14—C19—C18	−0.1 (6)
O1—C1—C2—O2	−62.7 (5)	C14—C15—C16—C17	2.0 (7)
N1—C1—C2—O2	119.1 (3)	C14—C15—C16—N2	−177.4 (4)
N1—C1—C2—C3	1.6 (2)	N2—C16—C17—C18	178.2 (4)
O1—C1—C2—C3	179.8 (4)	C15—C16—C17—C18	−1.2 (7)
O2—C2—C3—C14	1.6 (4)	C16—C17—C18—C19	−0.3 (7)
C1—C2—C3—C14	115.5 (3)	C17—C18—C19—C14	0.9 (7)
O2—C2—C3—N1	−115.4 (3)	N1—C20—C21—C22	60.0 (4)
C1—C2—C3—N1	−1.5 (2)	C20—C21—C22—N3	169.3 (3)
C2—C3—C14—C19	123.8 (4)	N3—C23—C24—O5	−56.3 (5)
N1—C3—C14—C15	45.4 (5)	O5—C25—C26—N3	58.4 (5)

D—H···A	D—H	H···A	D···A	D—H···A
C2—H2···O1i	0.98	2.46	3.229 (4)	135

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C2—H2⋯O1i	0.98	2.46	3.229 (4)	135

Symmetry code: (i) .