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Literature DB >> 25243949

Carbon dioxide reduction to methylamines under metal-free conditions.

Enguerrand Blondiaux¹, Jacky Pouessel, Thibault Cantat.

Abstract

The first metal-free catalysts are reported for the methylation of amines with carbon dioxide. Proazaphosphatrane superbases prove to be highly active catalysts in the reductive functionalization of CO2, in the presence of hydroboranes. The new methodology enables the methylation of N-H bonds in a wide variety of amines, including secondary amines, with increased chemoselectivity.

Entities: Chemical

Keywords: amines; boranes; carbon dioxide; organocatalysis; reduction

Year: 2014 PMID： 25243949 DOI： 10.1002/anie.201407357

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

7 in total

1. The spontaneous self-assembly of a molecular water pipe in 3D space.

Authors: Ian R Butler; Daniel M Evans; Peter N Horton; Simon J Coles; Stewart F Parker; Silvia C Capelli
Journal: IUCrJ Date: 2022-04-27 Impact factor: 5.588

2. Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO₂ in the Presence of Silylhalides.

Authors: Tongtong Wang; Maotong Xu; Andrew R Jupp; Zheng-Wang Qu; Stefan Grimme; Douglas W Stephan
Journal: Angew Chem Int Ed Engl Date: 2021-11-03 Impact factor: 16.823

3. Pincer-Supported Gallium Complexes for the Catalytic Hydroboration of Aldehydes, Ketones and Carbon Dioxide.

Authors: Lingyu Liu; Siu-Kwan Lo; Cory Smith; Jose M Goicoechea
Journal: Chemistry Date: 2021-10-27 Impact factor: 5.020

4. Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO₂, and hydrosilane catalyzed by 1,3,2-diazaphospholene?

Authors: Yu Lu; Zhong-Hua Gao; Xiang-Yu Chen; Jiandong Guo; Zheyuan Liu; Yanfeng Dang; Song Ye; Zhi-Xiang Wang
Journal: Chem Sci Date: 2017-09-11 Impact factor: 9.825

Carbon dioxide reduction to methylamines under metal-free conditions.

1. The spontaneous self-assembly of a molecular water pipe in 3D space.

2. Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO₂ in the Presence of Silylhalides.

3. Pincer-Supported Gallium Complexes for the Catalytic Hydroboration of Aldehydes, Ketones and Carbon Dioxide.

4. Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO₂, and hydrosilane catalyzed by 1,3,2-diazaphospholene?

Review 5. From CO₂ activation to catalytic reduction: a metal-free approach.

6. N,N-Dimethylation of nitrobenzenes with CO₂ and water by electrocatalysis.

7. A Molecular CO₂ Reduction Catalyst Based on Giant Polyoxometalate {Mo₃₆₈}.

Carbon dioxide reduction to methylamines under metal-free conditions.

1. The spontaneous self-assembly of a molecular water pipe in 3D space.

2. Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO2 in the Presence of Silylhalides.

3. Pincer-Supported Gallium Complexes for the Catalytic Hydroboration of Aldehydes, Ketones and Carbon Dioxide.

4. Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO2, and hydrosilane catalyzed by 1,3,2-diazaphospholene?

Review 5. From CO2 activation to catalytic reduction: a metal-free approach.

6. N,N-Dimethylation of nitrobenzenes with CO2 and water by electrocatalysis.

7. A Molecular CO2 Reduction Catalyst Based on Giant Polyoxometalate {Mo368}.

2. Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO₂ in the Presence of Silylhalides.

4. Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO₂, and hydrosilane catalyzed by 1,3,2-diazaphospholene?

Review 5. From CO₂ activation to catalytic reduction: a metal-free approach.

6. N,N-Dimethylation of nitrobenzenes with CO₂ and water by electrocatalysis.

7. A Molecular CO₂ Reduction Catalyst Based on Giant Polyoxometalate {Mo₃₆₈}.