Literature DB >> 25236504

Thermodynamics of halogen bonded monolayer self-assembly at the liquid-solid interface.

W Song1, N Martsinovich, W M Heckl, M Lackinger.   

Abstract

Monolayer self-assembly of a hexabrominated, three-fold symmetric aromatic molecule is studied at the heptanoic acid-graphite interface. Thermodynamical insights are obtained from an adapted Born-Haber cycle that is utilized to derive the overall enthalpy change including solvent effects. Comparison with theoretical entropy estimates suggests a minor influence of solvation.

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Year:  2014        PMID： 25236504     DOI： 10.1039/c4cc06251e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  A priori calculations of the free energy of formation from solution of polymorphic self-assembled monolayers.

Authors:  Jeffrey R Reimers; Dwi Panduwinata; Johan Visser; Yiing Chin; Chunguang Tang; Lars Goerigk; Michael J Ford; Maxine Sintic; Tze-Jing Sum; Michiel J J Coenen; Bas L M Hendriksen; Johannes A A W Elemans; Noel S Hush; Maxwell J Crossley
Journal:  Proc Natl Acad Sci U S A       Date:  2015-10-28       Impact factor: 11.205

2.  Self-Assembly under Confinement: Nanocorrals for Understanding Fundamentals of 2D Crystallization.

Authors:  Lander Verstraete; John Greenwood; Brandon E Hirsch; Steven De Feyter
Journal:  ACS Nano       Date:  2016-10-17       Impact factor: 15.881
  2 in total

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