| Literature DB >> 25225656 |
Awal Noor1, Sadaf Qayyum, Tobias Bauer, Stefan Schwarz, Birgit Weber, Rhett Kempe.
Abstract
A quintuply bonded dichromium complex stabilized by aminopyridinato ligands activates CO2 and SO2 by reducing the (formal) bond order of the metal-metal bonds. Oxygen abstraction is observed during CO2 activation. SO2 activation proceeds via formation of a unique dithionite complex/coordination. Furthermore, N2O activation was investigated and the formation of a tetrameric Cr-oxo complex was observed.Entities:
Year: 2014 PMID： 25225656 DOI： 10.1039/c4cc05071a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222