Literature DB >> 25225655

The crucial roles of MgCl2 as a non-innocent additive in the Ni-catalyzed carboxylation of benzyl halide with CO2.

Fareed Bhasha Sayyed1, Shigeyoshi Sakaki.   

Abstract

Ni-catalyzed carboxylation of the C(sp(3))-Cl bond with CO2 in the presence of MgCl2 was theoretically investigated. MgCl2 plays three crucial roles in stabilization of a Ni(I)-CO2 adduct and acceleration of the CO2 insertion as a non-innocent additive and the one-electron reduction process as one kind of reagent.

Entities:  

Year:  2014        PMID： 25225655     DOI： 10.1039/c4cc04962d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Development of an Improved System for the Carboxylation of Aryl Halides through Mechanistic Studies.

Authors:  David J Charboneau; Gary W Brudvig; Nilay Hazari; Hannah M C Lant; Andrew K Saydjari
Journal:  ACS Catal       Date:  2019-03-14       Impact factor: 13.084

2.  Nickel(I) Aryl Species: Synthesis, Properties, and Catalytic Activity.

Authors:  Megan Mohadjer Beromi; Gourab Banerjee; Gary W Brudvig; Nilay Hazari; Brandon Q Mercado
Journal:  ACS Catal       Date:  2018-02-13       Impact factor: 13.084

Review 3.  Metal-Catalyzed Carboxylation of Organic (Pseudo)halides with CO2.

Authors:  Marino Börjesson; Toni Moragas; Daniel Gallego; Ruben Martin
Journal:  ACS Catal       Date:  2016-08-30       Impact factor: 13.084

4.  Ni(I)-Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO2 Insertion at Ni(I) Centers.

Authors:  Rosie J Somerville; Carlota Odena; Marc F Obst; Nilay Hazari; Kathrin H Hopmann; Ruben Martin
Journal:  J Am Chem Soc       Date:  2020-06-12       Impact factor: 15.419

5.  Ni-catalyzed migratory fluoro-alkenylation of unactivated alkyl bromides with gem-difluoroalkenes.

Authors:  Lu Zhou; Chuan Zhu; Peijia Bi; Chao Feng
Journal:  Chem Sci       Date:  2018-11-09       Impact factor: 9.825

6.  Basicity as a Thermodynamic Descriptor of Carbanions Reactivity with Carbon Dioxide: Application to the Carboxylation of α,β-Unsaturated Ketones.

Authors:  Pietro Franceschi; Catia Nicoletti; Ruggero Bonetto; Marcella Bonchio; Mirco Natali; Luca Dell'Amico; Andrea Sartorel
Journal:  Front Chem       Date:  2021-11-24       Impact factor: 5.221

7.  Nickel-catalyzed electrochemical carboxylation of unactivated aryl and alkyl halides with CO2.

Authors:  Guo-Quan Sun; Wei Zhang; Li-Li Liao; Li Li; Zi-Hao Nie; Jin-Gui Wu; Zhen Zhang; Da-Gang Yu
Journal:  Nat Commun       Date:  2021-12-06       Impact factor: 14.919
  7 in total

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