| Literature DB >> 25223650 |
Ariela Burg1, Dror Shamir, Inna Shusterman, Haya Kornweitz, Dan Meyerstein.
Abstract
Kinetic and DFT results for the carbonate catalysed Co(H2O)6(2+) + H2O2 Fenton-like reaction suggest a mechanism involving the formation of a cyclic transient, cyclic-(CO4)Co(II)(OOH)(H2O)2(-) that decomposes into Co(II)(H2O)(OOH)(OH)2 + CO3˙(-), i.e. no OH˙ radicals are involved. Plausible biological implications are pointed out.Entities:
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Year: 2014 PMID： 25223650 DOI： 10.1039/c4cc05852f
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222