Literature DB >> 25223397

Rapid conversion of sorbitol to isosorbide in hydrophobic ionic liquids under microwave irradiation.

Akio Kamimura1, Kengo Murata, Yoshiki Tanaka, Tomoki Okagawa, Hiroshi Matsumoto, Kouji Kaiso, Makoto Yoshimoto.   

Abstract

Sorbitol was effectively converted to isosorbide by treatment with [TMPA][NTf2 ] in the presence of catalytic amounts of TsOH under microwave heating at 180 °C. The reaction completed within 10 min and isosorbide was isolated to about 60%. Ionic liquids were readily recovered by an extraction treatment and reused several times.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  biomass; ionic liquids; isosorbide; microwave chemistry; sorbitol

Mesh:

Substances:

Year:  2014        PMID: 25223397     DOI: 10.1002/cssc.201402655

Source DB:  PubMed          Journal:  ChemSusChem        ISSN: 1864-5631            Impact factor:   8.928


  3 in total

1.  Development of a microwave-assisted sustainable conversion of furfural hydrazones to functionalised phthalimides in ionic liquids.

Authors:  Valerija Karaluka; Kengo Murata; Shinto Masuda; Yuto Shiramatsu; Takuji Kawamoto; Helen C Hailes; Tom D Sheppard; Akio Kamimura
Journal:  RSC Adv       Date:  2018-06-20       Impact factor: 4.036

2.  Sustainable Synthesis of Chiral Tetrahydrofurans through the Selective Dehydration of Pentoses.

Authors:  Robert W Foster; Christopher J Tame; Dejan-Krešimir Bučar; Helen C Hailes; Tom D Sheppard
Journal:  Chemistry       Date:  2015-09-25       Impact factor: 5.236

3.  In Vivo Magnetic Resonance Imaging and Microwave Thermotherapy of Cancer Using Novel Chitosan Microcapsules.

Authors:  Shunsong Tang; Qijun Du; Tianlong Liu; Longfei Tan; Meng Niu; Long Gao; Zhongbing Huang; Changhui Fu; Tengchuang Ma; Xianwei Meng; Haibo Shao
Journal:  Nanoscale Res Lett       Date:  2016-07-15       Impact factor: 4.703

  3 in total

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