Literature DB >> 25217904

Measuring disorder in irreversible decay processes.

Shane W Flynn1, Helen C Zhao1, Jason R Green1.   

Abstract

Rate coefficients can fluctuate in statically and dynamically disordered kinetics. Here, we relate the rate coefficient for an irreversibly decaying population to the Fisher information. From this relationship we define kinetic versions of statistical-length squared and divergence that measure cumulative fluctuations in the rate coefficient. We show the difference between these kinetic quantities measures the amount of disorder, and is zero when the rate coefficient is temporally and spatially unique.

Entities:  

Year:  2014        PMID: 25217904     DOI: 10.1063/1.4895514

Source DB:  PubMed          Journal:  J Chem Phys        ISSN: 0021-9606            Impact factor:   3.488


  2 in total

1.  Fundamental Speed Limits to the Generation of Quantumness.

Authors:  Jun Jing; Lian-Ao Wu; Adolfo Del Campo
Journal:  Sci Rep       Date:  2016-11-30       Impact factor: 4.379

Review 2.  Dynamical Signatures of Multifunnel Energy Landscapes.

Authors:  David J Wales
Journal:  J Phys Chem Lett       Date:  2022-07-08       Impact factor: 6.888

  2 in total

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