Literature DB >> 25213194

Palladium(0)-catalyzed cross-coupling of 1,1-diboronates with vinyl bromides and 1,1-dibromoalkenes.

Huan Li1, Zhikun Zhang, Xianghang Shangguan, Shan Huang, Jun Chen, Yan Zhang, Jianbo Wang.   

Abstract

Palladium-catalyzed cross-coupling reactions of 1,1-diboronates with vinyl bromides and dibromoalkenes were found to afford 1,4-dienes and allenes, respectively. These reactions utilize the high reactivities of both 1,1-diboronates and allylboron intermediates generated in the initial coupling.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  alkenes; boron; cross-coupling; palladium; synthetic methods

Year:  2014        PMID： 25213194     DOI： 10.1002/anie.201407000

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  3 in total

1.  Enantioselective Copper-Catalyzed sp2/sp3 Diborylation of 1-Chloro-1-Trifluoromethylalkenes.

Authors:  Zhenwei Fan; Mingxing Ye; Yahao Wang; Jian Qiu; Wangyang Li; Xingxing Ma; Kai Yang; Qiuling Song
Journal:  ACS Cent Sci       Date:  2022-07-20       Impact factor: 18.728

2.  Nonracemic allylic boronates through enantiotopic-group-selective cross-coupling of geminal bis(boronates) and vinyl halides.

Authors:  Bowman Potter; Adam A Szymaniak; Emma K Edelstein; James P Morken
Journal:  J Am Chem Soc       Date:  2014-12-15       Impact factor: 15.419

3.  Copper-Catalyzed Triboration: Straightforward, Atom-Economical Synthesis of 1,1,1-Triborylalkanes from Terminal Alkynes and HBpin.

Authors:  Xiaocui Liu; Wenbo Ming; Yixiao Zhang; Alexandra Friedrich; Todd B Marder
Journal:  Angew Chem Int Ed Engl       Date:  2019-11-11       Impact factor: 15.336
  3 in total

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