Literature DB >> 25213038

Iodide-induced shuttling of a halogen- and hydrogen-bonding two-station rotaxane.

Antonio Caballero1, Laura Swan, Fabiola Zapata, Paul D Beer.   

Abstract

The first example of utilizing halogen-bonding anion recognition to facilitate molecular motion in an interlocked structure is described. A halogen-bonding and hydrogen-bonding bistable rotaxane is prepared and demonstrated to undergo shuttling of the macrocycle component from the hydrogen-bonding station to the halogen-bonding station upon iodide recognition. In contrast, chloride-anion binding reinforces the macrocycle to reside at the hydrogen-bonding station.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  anions; halogen bonding; molecular motion; rotaxanes; template synthesis

Year:  2014        PMID： 25213038     DOI： 10.1002/anie.201407580

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  7 in total

Review 1.  Artificial Molecular Machines.

Authors:  Sundus Erbas-Cakmak; David A Leigh; Charlie T McTernan; Alina L Nussbaumer
Journal:  Chem Rev       Date:  2015-09-08       Impact factor: 60.622

2.  A room temperature phosphorescence encoding [2]rotaxane molecular shuttle.

Authors:  Xiang Ma; Jing Zhang; Jingjing Cao; Xuyang Yao; Tiantian Cao; Yifan Gong; Chunchang Zhao; He Tian
Journal:  Chem Sci       Date:  2016-03-29       Impact factor: 9.825

3.  A redox-controllable molecular switch based on weak recognition of BPX26C6 at a diphenylurea station.

Authors:  Jia-Cheng Chang; Chien-Chen Lai; Sheng-Hsien Chiu
Journal:  Molecules       Date:  2015-01-22       Impact factor: 4.411

4.  Modulation of the Selectivity in Anions Recognition Processes by Combining Hydrogen- and Halogen-Bonding Interactions.

Authors:  Fabiola Zapata; Sergio J Benítez-Benítez; Paula Sabater; Antonio Caballero; Pedro Molina
Journal:  Molecules       Date:  2017-12-20       Impact factor: 4.411

5.  Superior anion induced shuttling behaviour exhibited by a halogen bonding two station rotaxane.

Authors:  Timothy A Barendt; Sean W Robinson; Paul D Beer
Journal:  Chem Sci       Date:  2016-04-28       Impact factor: 9.825

Review 6.  The Halogen Bond.

Authors:  Gabriella Cavallo; Pierangelo Metrangolo; Roberto Milani; Tullio Pilati; Arri Priimagi; Giuseppe Resnati; Giancarlo Terraneo
Journal:  Chem Rev       Date:  2016-01-26       Impact factor: 60.622

7.  Tetrel Bonding as a Vehicle for Strong and Selective Anion Binding.

Authors:  Steve Scheiner
Journal:  Molecules       Date:  2018-05-11       Impact factor: 4.411
  7 in total

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