Literature DB >> 25212674

Selective difluoroalkylation of alkenes by using visible light photoredox catalysis.

Chunghyeon Yu1, Naeem Iqbal, Sehyun Park, Eun Jin Cho.   

Abstract

A visible light-induced process for selective difluoroalkylation of unactivated alkenes has been developed. The choice of base is crucial for governing the chemoselectivity of the process to produce difluoroalkylated alkanes and alkenes.

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Year:  2014        PMID： 25212674     DOI： 10.1039/c4cc05467a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  12 in total

1.  Copper-Catalyzed Cyclopropanol Ring Opening Csp(3)-Csp(3) Cross-Couplings with (Fluoro)Alkyl Halides.

Authors:  Zhishi Ye; Kristen E Gettys; Xingyu Shen; Mingji Dai
Journal:  Org Lett       Date:  2015-12-04       Impact factor: 6.005

2.  Transition-Metal-Catalyzed Alkyl Heck-Type Reactions.

Authors:  Daria Kurandina; Padon Chuentragool; Vladimir Gevorgyan
Journal:  Synthesis (Stuttg)       Date:  2019-02-07       Impact factor: 3.157

3.  Palladium-catalyzed Heck-type reaction of secondary trifluoromethylated alkyl bromides.

Authors:  Tao Fan; Wei-Dong Meng; Xingang Zhang
Journal:  Beilstein J Org Chem       Date:  2017-12-06       Impact factor: 2.883

4.  HOTf-Catalyzed Alkyl-Heck-type Reaction.

Authors:  Huan Zhou; Liang Ge; Jinshuai Song; Wujun Jian; Yajun Li; Chunsen Li; Hongli Bao
Journal:  iScience       Date:  2018-05-01

Review 5.  Progress in Difluoroalkylation of Organic Substrates by Visible Light Photoredox Catalysis.

Authors:  Agostinho Lemos; Christian Lemaire; André Luxen
Journal:  Adv Synth Catal       Date:  2019-01-17       Impact factor: 5.837

6.  Visible-light Promoted Atom Transfer Radical Addition-Elimination (ATRE) Reaction for the Synthesis of Fluoroalkylated Alkenes Using DMA as Electron-Donor.

Authors:  Wen-Wen Xu; Le Wang; Ting Mao; Jiwei Gu; Xiao-Fei Li; Chun-Yang He
Journal:  Molecules       Date:  2020-01-24       Impact factor: 4.411

7.  (Fluoro)alkylation of alkenes promoted by photolysis of alkylzirconocenes.

Authors:  Xiaoxiao Ren; Xing Gao; Qiao-Qiao Min; Shu Zhang; Xingang Zhang
Journal:  Chem Sci       Date:  2022-03-02       Impact factor: 9.825

8.  Oxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF2H-Containing Alcohols.

Authors:  Yusuke Arai; Ren Tomita; Gaku Ando; Takashi Koike; Munetaka Akita
Journal:  Chemistry       Date:  2015-12-16       Impact factor: 5.236

9.  Visible-Light Photocatalytic Decarboxylation of α,β-Unsaturated Carboxylic Acids: Facile Access to Stereoselective Difluoromethylated Styrenes in Batch and Flow.

Authors:  Xiao-Jing Wei; Wout Boon; Volker Hessel; Timothy Noël
Journal:  ACS Catal       Date:  2017-09-11       Impact factor: 13.084

10.  Markovnikov-Type Hydrotrifluoromethylchalcogenation of Unactivated Terminal Alkenes with [Me4N][XCF3] (X = S, Se) and TfOH.

Authors:  Jin Shi; Cheng-Pan Zhang
Journal:  Molecules       Date:  2020-10-03       Impact factor: 4.411
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