Literature DB >> 25209443

[GaF3(BzMe2-tacn)]--a neutral 'metalloligand' towards alkali metal and ammonium cations in water.

Rajiv Bhalla1, William Levason, Sajinder K Luthra, Graeme McRobbie, Gillian Reid, George Sanderson, Wenjian Zhang.   

Abstract

The neutral complex, [GaF3(L)] (L = 1-benzyl-4,7-dimethyl-1,4,7-triazacyclononane, BzMe2-tacn), acts as a 'metalloligand' to Na(+), K(+) and [NH4](+) cations in aqueous solution, forming supramolecular assemblies containing significant Na/K-F and H3N(+)H···F coordination. κ(1)-[BF4](-) and κ(2)-[PF6](-) coordination is also evident to Na(+) and K(+), respectively.

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Year:  2014        PMID: 25209443     DOI: 10.1039/c4cc05603e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Rapid Aqueous Late-Stage Radiolabelling of [GaF3 (BnMe2 -tacn)] by 18 F/19 F Isotopic Exchange: Towards New PET Imaging Probes.

Authors:  Francesco M Monzittu; Imtiaz Khan; William Levason; Sajinder K Luthra; Graeme McRobbie; Gillian Reid
Journal:  Angew Chem Int Ed Engl       Date:  2018-04-26       Impact factor: 15.336

  1 in total

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