Literature DB >> 25204577

Copper-catalyzed phosphorylation of sp(2) C-H bonds.

Shan Wang1, Rui Guo, Gao Wang, Shan-Yong Chen, Xiao-Qi Yu.   

Abstract

The phosphorylation of the ortho C-H bonds in benzamides containing an 8-aminoquinoline moiety as a bidentate directing group with H-phosphonates using copper as a catalyst under mild temperature conditions is described. This method shows high functional group compatibility and selectively gives mono-substituted products.

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Year:  2014        PMID: 25204577     DOI: 10.1039/c4cc06246a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

1.  Palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C-S bond cleavage.

Authors:  Huijin Liu; Kai Sun; Xiaolan Li; Jie Zhang; Wei Lu; Xuzhong Luo; Haiqing Luo
Journal:  RSC Adv       Date:  2022-09-07       Impact factor: 4.036

2.  Copper-mediated oxidative C-H/N-H activations with alkynes by removable hydrazides.

Authors:  Feng Xiong; Bo Li; Chenrui Yang; Liang Zou; Wenbo Ma; Linghui Gu; Ruhuai Mei; Lutz Ackermann
Journal:  Beilstein J Org Chem       Date:  2021-07-08       Impact factor: 2.883

3.  Identification of monodentate oxazoline as a ligand for copper-promoted ortho-C-H hydroxylation and amination.

Authors:  Ming Shang; Qian Shao; Shang-Zheng Sun; Yan-Qiao Chen; Hui Xu; Hui-Xiong Dai; Jin-Quan Yu
Journal:  Chem Sci       Date:  2016-09-26       Impact factor: 9.825

  3 in total

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