Literature DB >> 25198920

Isolation and characterization of [5,6]-pyrrolidino-Sc₃N@I(h)-C₈₀ diastereomers.

Yutaka Maeda1, Masato Kimura, Chihiro Ueda, Michio Yamada, Toru Kikuchi, Mitsuaki Suzuki, Wei-Wei Wang, Naomi Mizorogi, Nikolaos Karousis, Nikos Tagmatarchis, Tadashi Hasegawa, Marilyn M Olmstead, Alan L Balch, Shigeru Nagase, Takeshi Akasaka.   

Abstract

Reactions of Sc3N@I(h)-C80 with aziridine derivatives were conducted to afford the corresponding mono-adducts. A pair of diastereomers of the mono-adduct [5,6]-pyrrolidino-Sc3N@I(h)-C80 was isolated and characterized by means of mass spectrometry, vis-NIR absorption spectroscopy, and electrochemical measurements. Structural analysis of the mono-adducts was conducted by NMR and single-crystal X-ray structure determinations.

Entities:  

Year:  2014        PMID: 25198920     DOI: 10.1039/c4cc04946b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

Review 1.  Functionalization of Endohedral Metallofullerenes with Reactive Silicon and Germanium Compounds.

Authors:  Masahiro Kako; Shigeru Nagase; Takeshi Akasaka
Journal:  Molecules       Date:  2017-07-14       Impact factor: 4.411

2.  Sc3N@I h -C80 based donor-acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation.

Authors:  Rubén Caballero; Luis David Servián; Habtom B Gobeze; Olivia Fernandez-Delgado; Luis Echegoyen; Francis D'Souza; Fernando Langa
Journal:  RSC Adv       Date:  2020-05-27       Impact factor: 4.036

  2 in total

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