Literature DB >> 25198244

High-temperature spin crossover in a mononuclear six-coordinate cobalt(II) complex.

Joanna Palion-Gazda1, Anna Świtlicka-Olszewska, Barbara Machura, Thais Grancha, Emilio Pardo, Francesc Lloret, Miguel Julve.   

Abstract

The six-coordinate cobalt(II) complex of formula [Co(tppz)2](tcm)2 exhibits a thermally induced spin-crossover behavior from a high spin (S = 3/2) at higher temperatures to a low spin (S = ½) at lower temperatures, with the low-spin phase being achieved at T ≤ 200 K.

Entities:  

Year:  2014        PMID： 25198244     DOI： 10.1021/ic501195y

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  2 in total

1.  Lanthanide nitrato complexes bridged by the bis-tridentate ligand 2,3,5,6-tetra(2-pyridyl)pyrazine: Syntheses, crystal structures, Hirshfeld surface analyses, luminescence properties, DFT calculations, and magnetic behavior.

Authors:  Li-Ling Cai; Sheng-Mei Zhang; Yan Li; Kai Wang; Xue-Ming Li; Gilles Muller; Fu-Pei Liang; Ya-Tao Hu; Gui-Xia Wang
Journal:  J Lumin       Date:  2020-12-15       Impact factor: 3.599

2.  Modulation of Mn3+ Spin State by Guest Molecule Inclusion.

Authors:  Irina A Kühne; Kane Esien; Laurence C Gavin; Helge Müller-Bunz; Solveig Felton; Grace G Morgan
Journal:  Molecules       Date:  2020-11-28       Impact factor: 4.411
  2 in total

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