Literature DB >> 25188876

Facilitating the Cope rearrangement by partial protonation: implications for synthesis and biosynthesis.

Phillip P Painter1, Bonnie M Wong, Dean J Tantillo.   

Abstract

The theoretical investigation of concerted and stepwise Cope rearrangements of natural products led to the prediction that some concerted Cope rearrangements can be promoted by noncovalent association of their transition state structures with ammonium cations.

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Year:  2014        PMID: 25188876     DOI: 10.1021/ol5023036

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Are boat transition states likely to occur in Cope rearrangements? A DFT study of the biogenesis of germacranes.

Authors:  José Enrique Barquera-Lozada; Gabriel Cuevas
Journal:  Beilstein J Org Chem       Date:  2017-09-19       Impact factor: 2.883

  1 in total

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