Literature DB >> 25179007

On the coordination chemistry of phosphinecarboxamide: assessing ligand basicity.

M B Geeson1, A R Jupp, J E McGrady, J M Goicoechea.   

Abstract

We describe the coordination chemistry of the primary phosphine PH2C(O)NH2 (phosphinecarboxamide) towards group 6 transition-metals. Experimental and theoretical studies reveal that this novel species has comparable electronic properties to PH3.

Entities:  

Year:  2014        PMID： 25179007     DOI： 10.1039/c4cc06094f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Exploiting the Brønsted acidity of phosphinecarboxamides for the synthesis of new phosphides and phosphines.

Authors:  Andrew R Jupp; Gemma Trott; Éléonore Payen de la Garanderie; James D G Holl; Duncan Carmichael; Jose M Goicoechea
Journal:  Chemistry       Date:  2015-04-17       Impact factor: 5.236

2.  A Monoanionic Arsenide Source: Decarbonylation of the 2-Arsaethynolate Anion upon Reaction with Bulky Stannylenes.

Authors:  Alexander Hinz; Jose M Goicoechea
Journal:  Angew Chem Int Ed Engl       Date:  2016-11-15       Impact factor: 15.336

3.  Synthesis of acyl(chloro)phosphines enabled by phosphinidene transfer.

Authors:  Kevin M Szkop; Michael B Geeson; Douglas W Stephan; Christopher C Cummins
Journal:  Chem Sci       Date:  2019-02-07       Impact factor: 9.825

4.  Synthesis and Characterization of Phosphinecarboxamide and Phosphinecarbothioamide, and Their Complexation with Palladium(II) Complex.

Authors:  Masumi Itazaki; Kento Okabayashi; Takanari Matsutani; Tomoya Nochida; Toshiyuki Moriuchi; Hiroshi Nakazawa
Journal:  Molecules       Date:  2022-08-29       Impact factor: 4.927

5.  Ambient-Temperature Synthesis of 2-Phosphathioethynolate, PCS-, and the Ligand Properties of ECX- (E = N, P; X = O, S).

Authors:  Andrew R Jupp; Michael B Geeson; John E McGrady; Jose M Goicoechea
Journal:  Eur J Inorg Chem       Date:  2015-11-04       Impact factor: 2.524

6.  Isolation of Au-, Co-η1PCO and Cu-η2PCO complexes, conversion of an Ir-η1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion.

Authors:  Liu Liu; David A Ruiz; Fatme Dahcheh; Guy Bertrand; Riccardo Suter; Aaron M Tondreau; Hansjörg Grützmacher
Journal:  Chem Sci       Date:  2016-01-04       Impact factor: 9.825
  6 in total

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