| Literature DB >> 25170976 |
Yoshiyuki Manabe1, Yuriko Kitawaki, Masahiro Nagasaki, Koichi Fukase, Hiroshi Matsubara, Yoshiko Hino, Takahide Fukuyama, Ilhyong Ryu.
Abstract
The photobromination of C-H bonds by using molecular bromine was reinvestigated under microfluidic conditions. The continuous-flow method suppressed the production of dibrominated compounds and effectively produced the desired monobrominated products with high selectivity. Rapid bromination of benzylic substrates containing a photoaffinity azide group was achieved without any decomposition.Entities:
Keywords: bromination; bromine; microreactors; photoreactions
Year: 2014 PMID： 25170976 DOI： 10.1002/chem.201402303
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236