Literature DB >> 25166709

Confinement as a tool to probe amorphous order.

Chiara Cammarota1, Giacomo Gradenigo1, Giulio Biroli1.   

Abstract

We study the effect of confinement on glassy liquids using random first order transition theory as a framework. We show that the characteristic length scale above which confinement effects become negligible is related to the point-to-set length scale introduced to measure the spatial extent of amorphous order in supercooled liquids. By confining below this characteristic size, the system becomes a glass. Eventually, for very small sizes, the effect of the boundary is so strong that any collective glassy behavior is wiped out. We clarify similarities and differences between the physical behaviors induced by confinement and by pinning particles outside a spherical cavity (the protocol introduced to measure the point-to-set length). Finally, we discuss possible numerical and experimental tests of our predictions.

Year:  2013        PMID: 25166709     DOI: 10.1103/PhysRevLett.111.107801

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  1 in total

1.  Solubility Limits in Lennard-Jones Mixtures: Effects of Disparate Molecule Geometries.

Authors:  Kippi M Dyer; John S Perkyns; B Montgomery Pettitt
Journal:  J Phys Chem B       Date:  2015-02-19       Impact factor: 2.991

  1 in total

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