Literature DB >> 25163768

The phosphaethynolate anion reacts with unsaturated bonds: DFT investigations into [2+2], [3+2] and [4+2] cycloadditions.

Liu Leo Liu1, Jun Zhu2, Yufen Zhao3.   

Abstract

Density functional theory (DFT) calculations were carried out to investigate the [2+2], [3+2] and [4+2] cycloadditions of the phosphaethynolate anion (PCO(-)). The results reveal that the electronic properties of different unsaturated compounds play a crucial role in reactivity and regioselectivity.

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Year:  2014        PMID： 25163768     DOI： 10.1039/c4cc04610b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Insights into the Competing Mechanisms and Origin of Enantioselectivity for N-Heterocyclic Carbene-Catalyzed Reaction of Aldehyde with Enamide.

Authors:  Yan Qiao; Xinhuan Chen; Donghui Wei; Junbiao Chang
Journal:  Sci Rep       Date:  2016-12-01       Impact factor: 4.379

2.  Making the unconventional μ2-P bridging binding mode more conventional in phosphinine complexes.

Authors:  Yuanfeng Hou; Zhongshu Li; Yaqi Li; Peng Liu; Cheng-Yong Su; Florian Puschmann; Hansjörg Grützmacher
Journal:  Chem Sci       Date:  2019-01-21       Impact factor: 9.825

3.  Understanding the Mechanism of Diels-Alder Reactions with Anionic Dienophiles: A Systematic Comparison of [ECX]- (E = P, As; X = O, S, Se) Anions.

Authors:  Ádám Horváth; Zoltán Benkő
Journal:  Inorg Chem       Date:  2022-05-09       Impact factor: 5.436

4.  Probing the Origin of Challenge of Realizing Metallaphosphabenzenes: Unfavorable 1,2-Migration in Metallapyridines Becomes Feasible in Metallaphosphabenzenes.

Authors:  Jingjing Wu; Yulei Hao; Jun Zhu
Journal:  Sci Rep       Date:  2016-06-24       Impact factor: 4.379

5.  The reactivity of acyl chlorides towards sodium phosphaethynolate, Na(OCP): a mechanistic case study.

Authors:  Dominikus Heift; Zoltán Benkő; Riccardo Suter; René Verel; Hansjörg Grützmacher
Journal:  Chem Sci       Date:  2016-06-17       Impact factor: 9.825

6.  Isolation of Au-, Co-η1PCO and Cu-η2PCO complexes, conversion of an Ir-η1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion.

Authors:  Liu Liu; David A Ruiz; Fatme Dahcheh; Guy Bertrand; Riccardo Suter; Aaron M Tondreau; Hansjörg Grützmacher
Journal:  Chem Sci       Date:  2016-01-04       Impact factor: 9.825
  6 in total

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