Literature DB >> 25138506

Aerobic Oxidation of Primary Alcohols by a New Mononuclear Cu(II) -Radical Catalyst.

P Chaudhuri1, M Hess, T Weyhermüller, K Wieghardt.   

Abstract

Primary alcohols such as ethanol or benzyl alcohol are selectively and catalytically oxidized by the mononuclear copper(II) radical complex 1-a functional model of the metalloenzyme galactose oxidase-with oxygen from air at 20°C to give the corresponding aldehydes and H2 O2 in about 60 % yield.
Copyright © 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Alcohols; Copper; Galactose oxidase; Homogeneous catalysis; Metalloenzymes

Year:  1999        PMID： 25138506     DOI： 10.1002/(SICI)1521-3773(19990419)38:8<1095::AID-ANIE1095>3.0.CO;2-I

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  20 in total

1.  The catalytic cycle of catechol oxidase.

Authors:  Per E M Siegbahn
Journal:  J Biol Inorg Chem       Date:  2004-06-05       Impact factor: 3.358

2.  Systematic development of computational models for the catalytic site in galactose oxidase: impact of outer-sphere residues on the geometric and electronic structures.

Authors:  Dalia Rokhsana; David M Dooley; Robert K Szilagyi
Journal:  J Biol Inorg Chem       Date:  2007-12-04       Impact factor: 3.358

Review 3.  Aerobic copper-catalyzed organic reactions.

Authors:  Scott E Allen; Ryan R Walvoord; Rosaura Padilla-Salinas; Marisa C Kozlowski
Journal:  Chem Rev       Date:  2013-06-20       Impact factor: 60.622

Review 4.  Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2 Model Systems to Organometallic Transformations.

Authors:  Rachel Trammell; Khashayar Rajabimoghadam; Isaac Garcia-Bosch
Journal:  Chem Rev       Date:  2019-01-30       Impact factor: 60.622

Review 5.  Copper active sites in biology.

Authors:  Edward I Solomon; David E Heppner; Esther M Johnston; Jake W Ginsbach; Jordi Cirera; Munzarin Qayyum; Matthew T Kieber-Emmons; Christian H Kjaergaard; Ryan G Hadt; Li Tian
Journal:  Chem Rev       Date:  2014-03-03       Impact factor: 60.622

6.  How useful are vibrational frequencies of isotopomeric O2 fragments for assessing local symmetry? Some simple systems and the vexing case of a galactose oxidase model.

Authors:  Christopher R Kinsinger; Benjamin F Gherman; Laura Gagliardi; Christopher J Cramer
Journal:  J Biol Inorg Chem       Date:  2005-11-08       Impact factor: 3.358

7.  Kinetics and DFT studies on the reaction of copper(II) complexes and H2O2.

Authors:  Takao Osako; Shigenori Nagatomo; Teizo Kitagawa; Christopher J Cramer; Shinobu Itoh
Journal:  J Biol Inorg Chem       Date:  2005-09-23       Impact factor: 3.358

8.  Characterization of the one-electron oxidized Cu(II)-salen complexes with a side chain aromatic ring: the effect of the indole ring on the Cu(II)-phenoxyl radical species.

Authors:  Hiromi Oshita; Takayoshi Yoshimura; Seiji Mori; Fumito Tani; Yuichi Shimazaki; Osamu Yamauchi
Journal:  J Biol Inorg Chem       Date:  2017-12-07       Impact factor: 3.358

9.  Mechanism of copper(I)/TEMPO-catalyzed aerobic alcohol oxidation.

Authors:  Jessica M Hoover; Bradford L Ryland; Shannon S Stahl
Journal:  J Am Chem Soc       Date:  2013-01-31       Impact factor: 15.419

10.  Mononuclear Cu-O2 complexes: geometries, spectroscopic properties, electronic structures, and reactivity.

Authors:  Christopher J Cramer; William B Tolman
Journal:  Acc Chem Res       Date:  2007-04-26       Impact factor: 22.384
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