Distribution of PCDD/Fs in the fly ash and atmospheric air of two typical hazardous waste incinerators in eastern China.

Distribution of polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) in the fly ash and atmospheric air of one medical waste incinerator (MWI) and one industrial hazardous waste incinerator (IHWI) plants were characterized. The PCDD/F concentrations of the stack gas (fly ash) produced from MWI and IHWI were 17.7 and 0.7 ng international toxic equivalent (I-TEQ)/Nm(3) (4.1 and 2.5 ng I-TEQ/g), respectively. For workplace air, the total concentrations of PCDD/Fs were 11.32 and 0.28 pg I-TEQ/Nm(3) (819.5 and 15.3 pg/Nm(3)). We assumed that the large differences of PCDD/F concentrations in workplace air were due to the differences in chlorine content of the waste, combustion conditions, and other contamination sources. With respect to the homologue profiles, the concentrations of PCDFs decreased with the increase of the substituted chlorine number for each site. Among all of the PCDD/F congeners, 2,3,4,7,8-PeCDF was the most important contributor to the I-TEQ value accounting for ca. 43 % of two sites. The gas/particle partition of PCDD/Fs in the atmosphere of the workplace in the MWI was also investigated, indicating that PCDD/Fs were more associated in the particle phase, especially for the higher chlorinated ones. Moreover, the ratio of the I-TEQ values in particle and gas phase of workplace air was 11.0. At last, the relationship between the distribution of PCDD/Fs in the workplace air and that from stack gas and fly ash was also analyzed and discussed. The high correlation coefficient might be a sign for diffuse gas emissions at transient periods of fumes escaping from the incinerator.