Literature DB >> 25123894

Direct hydrogenation of biomass-derived butyric acid to n-butanol over a ruthenium-tin bimetallic catalyst.

Jong-Min Lee1, Pravin P Upare, Jong-San Chang, Young Kyu Hwang, Jeong Ho Lee, Dong Won Hwang, Do-Young Hong, Seung Hwan Lee, Myung-Geun Jeong, Young Dok Kim, Young-Uk Kwon.   

Abstract

Catalytic hydrogenation of organic carboxylic acids and their esters, for example, cellulosic ethanol from fermentation of acetic acid and hydrogenation of ethyl acetate is a promising possibility for future biorefinery concepts. A hybrid conversion process based on selective hydrogenation of butyric acid combined with fermentation of glucose has been developed for producing biobutanol. ZnO-supported Ru-Sn bimetallic catalysts exhibits unprecedentedly superior performance in the vapor-phase hydrogenation of biomass-derived butyric acid to n-butanol (>98% yield) for 3500 h without deactivation.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  alcohols; biomass; carboxylic acids; hydrogenation; ruthenium

Mesh：

Substances：

Year:  2014        PMID： 25123894     DOI： 10.1002/cssc.201402311

Source DB:  PubMed          Journal:  ChemSusChem        ISSN： 1864-5631            Impact factor:   8.928


  8 in total

1.  Performance-advantaged ether diesel bioblendstock production by a priori design.

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Journal:  Proc Natl Acad Sci U S A       Date:  2019-12-16       Impact factor: 11.205

2.  Consolidated Bioprocessing for Butyric Acid Production from Rice Straw with Undefined Mixed Culture.

Authors:  Binling Ai; Xue Chi; Jia Meng; Zhanwu Sheng; Lili Zheng; Xiaoyan Zheng; Jianzheng Li
Journal:  Front Microbiol       Date:  2016-10-24       Impact factor: 5.640

3.  Metabolic engineering of Escherichia coli for the production of butyric acid at high titer and productivity.

Authors:  Liang Wang; Diane Chauliac; Brelan E Moritz; Guimin Zhang; Lonnie O Ingram; K T Shanmugam
Journal:  Biotechnol Biofuels       Date:  2019-03-22       Impact factor: 6.040

Review 4.  Renewable Butanol Production via Catalytic Routes.

Authors:  Heeyoung Choi; Jeehoon Han; Jechan Lee
Journal:  Int J Environ Res Public Health       Date:  2021-11-09       Impact factor: 3.390

Review 5.  Catalytic upgrading of butyric acid towards fine chemicals and biofuels.

Authors:  Magnus Sjöblom; Leonidas Matsakas; Paul Christakopoulos; Ulrika Rova
Journal:  FEMS Microbiol Lett       Date:  2016-03-17       Impact factor: 2.742

6.  High-effective approach from amino acid esters to chiral amino alcohols over Cu/ZnO/Al2O3 catalyst and its catalytic reaction mechanism.

Authors:  Shuangshuang Zhang; Jun Yu; Huiying Li; Dongsen Mao; Guanzhong Lu
Journal:  Sci Rep       Date:  2016-09-13       Impact factor: 4.379

7.  Hydrogenation of Lactic Acid to 1,2-Propanediol over Ru-Based Catalysts.

Authors:  Kaituo Liu; Xiaoming Huang; Evgeny A Pidko; Emiel J M Hensen
Journal:  ChemCatChem       Date:  2018-01-15       Impact factor: 5.686

8.  Enhanced extraction of butyric acid under high-pressure CO2 conditions to integrate chemical catalysis for value-added chemicals and biofuels.

Authors:  Jaesung Chun; Okkyoung Choi; Byoung-In Sang
Journal:  Biotechnol Biofuels       Date:  2018-04-23       Impact factor: 6.040
  8 in total

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