Siderophile element constraints on the origin of the Moon.

Discovery of small enrichments in (182)W/(184)W in some Archaean rocks, relative to modern mantle, suggests both exogeneous and endogenous modifications to highly siderophile element (HSE) and moderately siderophile element abundances in the terrestrial mantle. Collectively, these isotopic enrichments suggest the formation of chemically fractionated reservoirs in the terrestrial mantle that survived the putative Moon-forming giant impact, and also provide support for the late accretion hypothesis. The lunar mantle sources of volcanic glasses and basalts were depleted in HSEs relative to the terrestrial mantle by at least a factor of 20. The most likely explanations for the disparity between the Earth and Moon are either that the Moon received a disproportionately lower share of late accreted materials than the Earth, such as may have resulted from stochastic late accretion, or the major phase of late accretion occurred prior to the Moon-forming event, and the putative giant impact led to little drawdown of HSEs to the Earth's core. High precision determination of the (182)W isotopic composition of the Moon can help to resolve this issue.