Literature DB >> 25113074

Synthesis of soluble, alkyne-substituted trideca- and hexadeca-starphenes.

Elias C Rüdiger1, Michael Porz, Manuel Schaffroth, Frank Rominger, Uwe H F Bunz.   

Abstract

Two literature-known TIPS-ethynyl-dibromoacenes were prepared and employed to synthesize cyclotrimers by using Yamamoto coupling conditions. Two large, well-soluble starphenes were isolated in good yields. Crystallographic characterization verifies the triangular shape and shows significant differences in crystal packing.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  Yamamoto coupling; density functional calculations; pi interactions; starphenes; synthetic methods

Year:  2014        PMID： 25113074     DOI： 10.1002/chem.201403697

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  4 in total

1.  Selective access to either a doubly boron-doped tetrabenzopentacene or an oxadiborepin from the same precursor.

Authors:  Julian Radtke; Kai Schickedanz; Marcel Bamberg; Luigi Menduti; Dieter Schollmeyer; Michael Bolte; Hans-Wolfram Lerner; Matthias Wagner
Journal:  Chem Sci       Date:  2019-07-31       Impact factor: 9.825

2.  Preparation of substituted triphenylenes via nickel-mediated Yamamoto coupling.

Authors:  Zachary W Schroeder; Joshua LeDrew; Vanessa M Selmani; Kenneth E Maly
Journal:  RSC Adv       Date:  2021-12-13       Impact factor: 4.036

3.  Persistent Ambipolar Heptacenes and Their Redox Species.

Authors:  Nico Zeitter; Nikolai Hippchen; Steffen Maier; Frank Rominger; Andreas Dreuw; Jan Freudenberg; Uwe H F Bunz
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-05       Impact factor: 16.823

Review 4.  Diels-Alder Cycloaddition to the Bay Region of Perylene and Its Derivatives as an Attractive Strategy for PAH Core Expansion: Theoretical and Practical Aspects.

Authors:  Aneta Kurpanik; Marek Matussek; Piotr Lodowski; Grażyna Szafraniec-Gorol; Michał Krompiec; Stanisław Krompiec
Journal:  Molecules       Date:  2020-11-17       Impact factor: 4.411
  4 in total

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