Literature DB >> 25111358

Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons.

Richard A Lewis1, K Cory MacLeod, Brandon Q Mercado, Patrick L Holland.   

Abstract

A low-coordinate iron(I) species can reversibly reduce pyridine, either by one electron to give a new C-C bond, or by two electrons to give a pyridine-derived bridge with an unprecedented μ-η(1):η(3) binding mode.

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Year:  2014        PMID： 25111358      PMCID： PMC4169077          DOI： 10.1039/c4cc05495d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  11 in total

1.  Reversible sigma C-C bond formation between phenanthroline ligands activated by (C5Me5)2Yb.

Authors:  Grégory Nocton; Wayne W Lukens; Corwin H Booth; Sergio S Rozenel; Scott A Medling; Laurent Maron; Richard A Andersen
Journal:  J Am Chem Soc       Date:  2014-06-09       Impact factor: 15.419

2.  Electronic structure of 2,2'-bipyridine organotransition-metal complexes. Establishing the ligand oxidation level by density functional theoretical calculations.

Authors:  Christopher C Scarborough; Karl Wieghardt
Journal:  Inorg Chem       Date:  2011-06-16       Impact factor: 5.165

3.  Manifestations of noninnocent ligand behavior.

Authors:  Wolfgang Kaim
Journal:  Inorg Chem       Date:  2011-07-11       Impact factor: 5.165

4.  Electronically unsaturated three-coordinate chloride and methyl complexes of iron, cobalt, and nickel.

Authors:  Patrick L Holland; Thomas R Cundari; Lanyn L Perez; Nathan A Eckert; Rene J Lachicotte
Journal:  J Am Chem Soc       Date:  2002-12-04       Impact factor: 15.419

5.  New complexes of chromium(III) containing organic π-radical ligands: an experimental and density functional theory study.

Authors:  Mei Wang; Jason England; Thomas Weyhermüller; Swarna-Latha Kokatam; Christopher J Pollock; Serena DeBeer; Jingmei Shen; Glenn P A Yap; Klaus H Theopold; Karl Wieghardt
Journal:  Inorg Chem       Date:  2013-03-26       Impact factor: 5.165

6.  Iron(II) complexes with redox-active tetrazene (RNNNNR) ligands.

Authors:  Ryan E Cowley; Eckhard Bill; Frank Neese; William W Brennessel; Patrick L Holland
Journal:  Inorg Chem       Date:  2009-06-01       Impact factor: 5.165

7.  Multiple pathways for dinitrogen activation during the reduction of an Fe Bis(iminepyridine) complex.

Authors:  Jennifer Scott; Indu Vidyaratne; Ilia Korobkov; Sandro Gambarotta; Peter H M Budzelaar
Journal:  Inorg Chem       Date:  2008-01-04       Impact factor: 5.165

8.  A bridging hexazene (RNNNNNNR) ligand from reductive coupling of azides.

Authors:  Ryan E Cowley; Jérôme Elhaïk; Nathan A Eckert; William W Brennessel; Eckhard Bill; Patrick L Holland
Journal:  J Am Chem Soc       Date:  2008-04-18       Impact factor: 15.419

9.  Reversible C-C bond formation between redox-active pyridine ligands in iron complexes.

Authors:  Thomas R Dugan; Eckhard Bill; K Cory MacLeod; Gemma J Christian; Ryan E Cowley; William W Brennessel; Shengfa Ye; Frank Neese; Patrick L Holland
Journal:  J Am Chem Soc       Date:  2012-12-11       Impact factor: 15.419

10.  A multi-iron system capable of rapid N2 formation and N2 cleavage.

Authors:  K Cory MacLeod; David J Vinyard; Patrick L Holland
Journal:  J Am Chem Soc       Date:  2014-07-08       Impact factor: 15.419
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  9 in total

1.  Crystallographic Characterization and Non-Innocent Redox Activity of the Glycine Modified DOTA Scaffold and Its Impact on EuIII Electrochemistry.

Authors:  Marianne E Burnett; Bukola Adebesin; S James Ratnakar; Kayla N Green
Journal:  Eur J Inorg Chem       Date:  2018-03-23       Impact factor: 2.524

2.  Diazoalkanes in Low-Coordinate Iron Chemistry: Bimetallic Diazoalkyl and Alkylidene Complexes of Iron(II).

Authors:  Megan E Reesbeck; Katarzyna Grubel; Daniel Kim; William W Brennessel; Brandon Q Mercado; Patrick L Holland
Journal:  Inorg Chem       Date:  2017-01-09       Impact factor: 5.165

3.  C-H and C-N Activation at Redox-Active Pyridine Complexes of Iron.

Authors:  K Cory MacLeod; Richard A Lewis; Daniel E DeRosha; Brandon Q Mercado; Patrick L Holland
Journal:  Angew Chem Int Ed Engl       Date:  2016-12-21       Impact factor: 15.336

4.  Reversible Ligand-Centered Reduction in Low-Coordinate Iron Formazanate Complexes.

Authors:  Daniël L J Broere; Brandon Q Mercado; James T Lukens; Avery C Vilbert; Gourab Banerjee; Hannah M C Lant; Shin Hee Lee; Eckhard Bill; Stephen Sproules; Kyle M Lancaster; Patrick L Holland
Journal:  Chemistry       Date:  2018-06-07       Impact factor: 5.236

5.  Dinitrogen Activation and Functionalization using β-Diketiminate Iron Complexes.

Authors:  Samuel M Bhutto; Patrick L Holland
Journal:  Eur J Inorg Chem       Date:  2019-04-01       Impact factor: 2.524

6.  Masked Radicals: Iron Complexes of Trityl, Benzophenone, and Phenylacetylene.

Authors:  K Cory MacLeod; Ida M DiMucci; Edward P Zovinka; Sean F McWilliams; Brandon Q Mercado; Kyle M Lancaster; Patrick L Holland
Journal:  Organometallics       Date:  2019-10-10       Impact factor: 3.876

7.  Structural, Theoretical Investigations, Hirshfeld Surface Analysis, and Cytotoxicity Profile of a Neocuproine-Co(II)-Based Discrete Homodinuclear Complex.

Authors:  Mohd Muslim; Farha Naz; Abdullah Alarifi; Mohd Afzal; Nayim Sepay; Musheer Ahmad
Journal:  Appl Biochem Biotechnol       Date:  2022-10-11       Impact factor: 3.094

8.  Density Functional Calculations for Prediction of 57Fe Mössbauer Isomer Shifts and Quadrupole Splittings in β-Diketiminate Complexes.

Authors:  Sean F McWilliams; Emma Brennan-Wydra; K Cory MacLeod; Patrick L Holland
Journal:  ACS Omega       Date:  2017-06-12

9.  Functionalized pyridine in pyclen-based iron(iii) complexes: evaluation of fundamental properties.

Authors:  Magy A Mekhail; Kristof Pota; Timothy M Schwartz; Kayla N Green
Journal:  RSC Adv       Date:  2020-08-26       Impact factor: 3.361
  9 in total

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